Composition for skin or hair
AssigneeShiseido Company, Ltd.
InventorsNozomi Oguchi, Yukie Yoda, Hiroyuki Kakoki
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AssigneeShiseido Company, Ltd.
InventorsNozomi Oguchi, Yukie Yoda, Hiroyuki Kakoki
Estimating the term…
The present invention provides a composition for skin or hair which achieves an excellent UV absorption in a wide range of UV wavelength from the UV-A to the UV-B without inhibiting the effect of the alkyl β,β-diphenylacrylate and the α-cyano-β,β-diphenylacrylate (e.g. octocrylene) which serve to improve the photostability of dibenzoylmethane derivative. The composition for skin or hair comprises: (a) a dibenzoylmethane derivative, (b) an alkyl β,β-diphenylacrylate and/or an α-cyano-β,β-diphenylacrylate (e.g. octocrylene), and (c) a specific benzalmalonate derivative (e.g. di(2-ethylhexyl)-4-methoxybenzalmalonate).
A composition for skin or hair comprising;
Dependencies are inferred from the claim text.
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Containing oxygen: esters of carboxylic acids
Containing oxygen: ketones, e.g. benzophenone
Containing organic compounds: containing nitrogen
Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g.…
About 2 years 3 months of term left · ends 30 Jan 2029 (estimated)
This application claims the priority of Japanese Patent Application No. 2007-44764 filed on Feb. 23, 2007, which is incorporated herein by reference.
The present invention relates to a composition for external use on skin or hair. Particularly, the present invention relates to the composition for skin or hair which achieves a highly excellent stability (photostability) and an excellent UV absorption over a wide UV wavelength range from UV-A to UV-B. The present invention is preferably applied to sunscreen cosmetics.
UV absorbers are blended in cosmetics to protect human skin from UV radiation or to prevent degradation of components due to UV rays.
FIG. 1 is a graph showing an absorbance of the compound obtained in Synthesis Example 1, that is, di(2-ethylhexyl)-4-methoxybenzalmalonate represented in formula (II).
The present invention will be further detailed in the following.
For component (a), one or more kinds of dibenzoylmethane derivatives known as UV absorbers are used. In the present invention, 4-tert-butyl-4′-methoxydibenzoylmethane is particularly preferred. 4-tert-butyl-4′-methoxydibenzoylmethane is, for example, commercially available from DSM Nutritional Products, Inc. under the commercial name of “Parsol 1789”, which can be used in the present invention.
The blending amount of component (a) is preferably from 0.01 to 10% by mass with respect to the composition of the present invention, more preferably from 0.3 to 5% by mass. If the blending amount of component (a) is less than 0.01% by mass, it is difficult to achieve a sufficient UV absorption. On the other hand, for cosmetics or preparations for external use on skin, 10% by mass of component (a) is enough to achieve a sufficient UV absorption. If component (a) is blended in the amount of more than 10% by mass, the effect is not improved in proportion to the increase of blending amount, which is not economical.