A fumigation system, comprising a sorbent-based and/or internal regulator-equipped supply vessel holding phosphine and coupled with a dispensing assembly, wherein the supply vessel and dispensing assembly are adapted to contain phosphine in the supply vessel for dispensing phosphine gas at subatmospheric or low superatmospheric pressure from the dispensing assembly, and a mixing assembly coupled in fluid flow communication with the dispensing assembly, wherein said mixing assembly is adapted to mix dispensed phosphine gas from the dispensing assembly with a carrier gas in relative proportions producing a phosphine/carrier gas mixture in which phosphine is diluted to non-flammable concentration in a range of from 2 ppm to 2% in the mixture, and to discharge the phosphine/carrier gas mixture for fumigation use, wherein the carrier gas is selected from the group consisting of air, carbon dioxide, and inert gas.