Polyimide optical article

An article comprising a concave lens wherein the lens has a width of 0.1 millimeter to 100 millimeter, a length of 0.5 millimeter to 500 millimeters, and a thickness of 0.2 millimeter to 5 millimeter;

• wherein the lens transmits light having a wavelength of 850 nanometers to 1550 nanometers wherein the lens comprises a polymer and the polymer comprises a polyimide comprising structural units derived from
• (A) a dianhydride/diamine pair wherein the pair comprises
• (i) oxydiphthalic anhydride and diaminodiphenylsulfone, or
• (ii) a dianhydride selected from the group consisting of oxydiphthalic anhydride, 3,3, bisphenol A dianhydride, 4,4, bisphenol A dianhydride, and combinations of the foregoing dianhydrides and a diamine selected from the group consisting of meta-phenylenediamine, para-phenylenediamine, diaminodiphenyl sulfone, oxydianiline, and combinations of the foregoing diamines,
• (B) a chloro-substituted phthalic anhydride, a diamine selected from the group consisting of meta-phenylenediamine, para-phenylenediamine, diaminodiphenyl sulfone, oxydianiline and combinations thereof, and a dihydroxy phenol salts, or
• (C) a combination selected from the group of (A) and (B);
• and
• wherein the lens is transparent and dimensionally stable at a wall thickness of at least 0.2 millimeters to 5.0 millimeters and remains transparent and dimensionally stable after being (a) exposed to a precondition of 60° C./60% relative humidity for 120 hours and (b) then subjected to a lead free solder test having a peak temperature of 260° C. for up to 30 seconds.