A method for separating a feed stream, comprising at least H2S, CO and H2, into at least a CO2 product stream and an H2 or H2 and CO product stream (the “H2/CO product stream”), wherein the feed stream is formed from a sour syngas stream obtained from gasification of a solid or liquid carbonaceous feedstock and is separated using a pressure swing adsorption system (the “H2/CO-PSA system”), an H2S removal system, and a further separation system, and wherein:
- the feed stream is introduced into either the H2/CO-PSA system or the H2S removal system;
- the H2/CO-PSA system either separates the feed stream to provide the H2/CO product stream and a stream enriched in CO2 and H2S, or separates a stream already depleted in H2S by the H2S removal system to provide the H2/CO product stream and a stream enriched in CO2 and depleted in H2S;
- the H2S removal system either processes the feed stream to provide a stream depleted in H2S, or processes a stream already enriched in CO2 and H2S by the H2/CO-PSA system to provide a stream enriched in CO2 and depleted in H2S, or processes a stream already enriched in CO2 and H2S by the H2/CO-PSA system and further enriched in CO2 and H2S by the further separation system to provide the CO2 product stream;
- and
- the further separation system either separates a stream already enriched in CO2 and H2S by the H2/CO-PSA system to provide a stream further enriched in CO2 and H2S and a stream comprising H2 or H2 and CO, or separates a stream already enriched in CO2 by the H2/CO-PSA system and depleted in H2S by the H2S removal system to provide the CO2 product stream and a stream comprising H2 or H2 and CO.