Conversion of nitrile compounds into corresponding carboxylic acids and esters
AssigneeRhodia Operations
InventorsOlivier Buisine, Philippe Leconte, Melanie Agati
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Abstract
Hydrocarbon compounds having at least one nitrile function are converted into compounds having at least one carboxylic function by hydrating the nitrile functions into amide functions by reaction with water in the presence of a strong inorganic acid, and then hydrolyzing the amide functions into carboxylic functions by reaction with water and a strong inorganic acid; the carboxylic compounds thus obtained can be esterified into diesters, advantageously diester solvents.
Claims20
A process for the production of a carboxylic acid having from 4 to 10 carbon atoms by hydrating the nitrile functional groups of an organic compound into amide functional groups and hydrolysis of such amide functional groups into carboxyl functional groups, and which comprises:
- conducting said hydration stage by reaction with water in the presence of a strong inorganic acid employing from 1 to 1.5 mol of water per mole of nitrile functional group to be hydrated, in the presence of a strong inorganic acid, at a temperature which maintains the reaction medium in the liquid state;
- conducting said hydrolysis stage with stirring employing from 1 to 10 mol of water per mole of amide functional group to be hydrolyzed and an amount of strong inorganic acid, expressed as protons and corresponding to at least 1 mol of protons per mole of amide to be hydrolyzed, the temperature of the reaction medium being such as to maintain the reaction medium in the liquid state;
- and
- recovering the carboxylic acid thus formed by maintaining the reaction medium, without stirring, at a temperature greater than the melting point of the carboxylic acid and/or of the salt formed to separate the reaction medium by settling into an upper phase and a lower phase and recovering the upper phase comprising the carboxylic acid.
Dependencies are inferred from the claim text.