Hydrolysis resistant organomodified trisiloxane ionic surfactants

A composition comprising a siloxane having the formula:

• M1D M2
• wherein
• M1=(R1)(R2)(R3)SiO1/2;
• M2=(R4)(R5)(R6)SiO1/2 and
• D=(R7)(Z)SiO2/2
• where R1, R2, R3, R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group;
• Z is a hydrophilic substituent R9−Rc;
• R9 is a monovalent radical selected from the group consisting of R16(O)w(R17)x and R18O(C2H4O)d(C3H6O)e(C4H8O)fCH2CH(OH)CH2;
• where R16 and R17 are each independently selected from the group consisting of a divalent hydrocarbon group of 1 to 4 carbon atoms, that may each be optionally substituted with one or more OH radicals;
• R18 is a divalent hydrocarbon group of 2 to 4 carbon atoms;
• subscripts w and x are zero or 1;
• the subscripts d, e and f are zero or positive and satisfy the following relationships:
• 1≦d+e+f≦10 with d≧1;
• RC is selected from the group consisting of N(R19)(R20),
• where R19 and R20 are independently selected from the group consisting of H, a branched or linear monovalent hydrocarbon radical of 1 to 4 carbons, R26N(R29)(R30), and —R27O(C2H4O)g(C3H6O)h(C4H8O)iR28;
• the subscripts g, h and i are zero or positive and satisfy the following relationships:
• 1≦g+h+i≦10 with g≧1;
• R21, R23, R24, R25 are independently selected from the groups consisting of H, a branched or linear monovalent hydrocarbon radical of 1 to 4 carbons;
• R22 is H, a branched or linear monovalent hydrocarbon radical of 1 to 4 carbons, or —R31O(C2H4O)j(C3H6O)k(C4H8O)lR32;
• the subscripts j, k and l are zero or positive and satisfy the following relationships:
• 1≦j+k+l≦10 with j≧1;
• R26 is a divalent hydrocarbon radical of 1 to 6 carbons that may be optionally substituted with a heterocyclic group containing nitrogen, sulfur, oxygen or combinations thereof or R33O(C2H4O)m(C3H6O)n(C4H8O)oR34;
• the subscripts m, n and o are zero or positive and satisfy the following relationships:
• 1≦m+n+o≦10 with m≧1;
• R29 and R30 are independently selected from the group consisting of H or a branched or linear monovalent hydrocarbon radical of 1 to 4 carbons;
• R27, R31 and R33 are divalent radicals independently selected from the group consisting of a divalent hydrocarbon group of 2 to 4 carbon atoms;
• R28 is H, a monovalent hydrocarbon radical of 1 to 6 carbons, or N(R35)(R36);
• R32 and R34 are independently selected from the group consisting of H, a branched or linear monovalent hydrocarbon radical of 1 to 4 carbons, and R37N(R38)(R39);
• where R37 is a divalent hydrocarbon radical of 1 to 6 carbons;
• R35, R36, R38 and R39 are independently selected from the group consisting of H and branched or linear monovalent hydrocarbon radicals of 1 to 4 carbons.