Aqueous dispersions of heavy oil residues
AssigneeEnitecnologie S.p.A.
InventorsArmando Marcotullio, Riccardo Rausa, Alessandro Lezzi
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Abstract
A description follows of an aqueous dispersion of heavy oil residues, suitable for undergoing combustion with a low emission of SOx, comprising: (a) a heavy oil residue; (b) a dispersing agent; (c) a desulfurizing agent selected from CaCO3, MgCO3, dolomite and relative mixtures; (d) a desulfurizing agent with stabilizing and anti-corrosive properties selected from MgO, Mg(OH)2, CaO, Ca(OH)2 and relative mixtures; (e) water; the weight percentage of (e) with respect of the sum of (a)+(e) being at least 15%.
Claims5
A process for combustion of heavy oil residues with a low emission of SOx comprising:
- heating the heavy oil residues at a temperature at least equal to a softening point of the heavy oil residues;
- preparing a dispersion of the heated heavy oil residues in water, and
- combusting the dispersion of the heavy oil residues in water;
- wherein the heavy oil residues have a softening point higher than 25° C., and
- wherein the dispersion of the heavy oil residues in water comprises:
- one or more dispersing agents selected from organic sulfonates of alkali metals or of ammonium;
- one or more desulfurizing agents selected from the group consisting of CaCO3, MgCO3, dolomite and relative mixtures;
- and
- one or more desulfurizing agents with stabilizing and anticorrosive properties selected from the group consisting of MgO, Mg (OH)2, CaO, Ca(OH)2 and relative mixtures;
- wherein
- the dispersion of heavy oil residue in water has a water content of at least 15%,
- the dispersing agent in the form of the sodium salt has the following properties:
- (A) a sulfur content of at least 10% by weight;
- (B) a solubility in water at 20° C. of at least 15% by weight;
- (C) a reduction in the surface tension in water, at a concentration of 1% by weight, lower than 10%;
- the desulfurizing agents are present in a quantity ranging from 0.5 to 3.0 moles with respect to the sulfur contained in the heavy oil residue, and
- the desulfurizing agents with stabilizing and anticorrosive properties are present in a quantity ranging from 0.04% by weight to 0.4% by weight with respect to the total suspension.
Dependencies are inferred from the claim text.