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US 8,242,319 B1Granted
Selective isomerization and oligomerization of olefin feedstocks for the production of turbine and diesel fuels
AssigneeThe United States of America as represented by the Secretary of the Navy
InventorsBenjamin G. Harvey, Michael E. Wright
Life of this patent
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Abstract
A process from converting alcohol feedstock to diesel/turbine fuels.
Claims18
A process for manufacturing turbine and/or diesel fuels, comprising:
- providing an alcohol feedstock;
- dehydrating said alcohol with at least one solid catalyst at temperatures ranging from about 200° C. to about 400° C. to produce an olefin mixture;
- oligomizering said mixture directly with at least one metallocene based Ziegler Natta catalyst and methylaluminoxane (MAO) cocatalyst to produce an oligomer mixture including unreacted internal olefins and oligomers;
- separating said unreacted olefins by temperature controlled distillation;
- converting said unreacted olefins to a distribution of oligomers with a bimetallic isomerization/oligomerization catalyst having a metallocene based catalyst in conjunction with an isomerization catalyst to produce oligomers formed through 1,2-addition;
- and hydrogenating and distilling said oligomers to produce fully saturated diesel and turbine fuels.
3 more elements
Dependencies are inferred from the claim text.