Two-paste type dental self-adhesive resin cement
AssigneeShofu Inc.
InventorsYoshiaki Kohro, Hisaki Tanaka, Keisuke Torii, Toshiyuki Nakatsuka, Mikito Deguchi
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Abstract
The present invention provides a dental self-adhesive resin cement having clinically-acceptable adherability for various adherends without pre-treatment with primers. Specifically, there is provided the dental self-adhesive composite resin cement comprising: (a) a radical polymerizable monomer, (b) a polymerizable monomer having a phosphonic acid group and/or a phosphoric acid ester group, (c) a polymerizable monomer having a dibasic acid carboxyl group, (d) a filler, and (e) a polymerization catalyst.
Claims1
A two-paste type dental self-adhesive composite resin cement consisting of a first paste and a second paste, which exhibits an effective shear bond strength for dentin,
- wherein, the first paste comprises, on a basis of 50% by weight of the first paste:
- (a)-(1) 8.0-22.5% by weight of a radical polymerizable monomer,
- (d)-(1) 27.45-40.0% by weight of a filler, and
- (e)-(1) 0.025-1.0% by weight of an alkali metal salt or an alkaline earth metal salt of barbituric acid and/or 0.025-0.5% by weight of aromatic secondary or tertiary amine, and
- the second paste comprises, on a basis of 50% by weight of the second paste:
- (a)-(2) 5.0-22.5% by weight of a second radical polymerizable monomer,
- (b) 0.05-3.0% by weight of a polymerizable monomer having a phosphonic acid group represented by formula [I]:
- wherein R1 is a hydrogen atom or a methyl group, R2 is an alkylene group of the carbon atom number of 5-10, and R3 is an alkylene group of the carbon atom number 1-6,
- (c) 0.05-3.0% by weight of a polymerizable monomer having a dibasic acid carboxyl group,
- (d)-(2) 27.3-40.0% by weight of a second filler, and
- (e)-(2) 0.3-0.8% by weight of a chemical polymerization initiator and/or a photopolymerization initiator, and wherein both of the pastes are free from water.
Dependencies are inferred from the claim text.