# US 8,148,795 B2 · Functional device

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- Number: US 8,148,795 B2
- Document ID: US8148795B2
- Status: Granted
- Kind: B2
- Application number: 11/653,642
- Filed: 2007-01-16
- Published: 2007-12-13
- Granted: 2012-04-03
- Earliest claimed: 2006-01-19
- Assignees: Sony Corporation
- Inventors: Masahiro Morooka; Yusuke Suzuki; Reiko Ogura
- Web page: https://patentgrep.com/patent/US8148795B2

## CPC

- H10W 74/131: {the semiconductor body being only partially enclosed}
- H01G 9/2077: {Sealing arrangements, e.g. to prevent the leakage of the electrolyte}
- H10F 77/50: Encapsulations or containers (for photovoltaic modules H10F19/80)
- H01G 9/2031: {comprising titanium oxide, e.g. TiO2 (H01G9/2036 takes precedence)}
- H01G 9/2059: {comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution}
- H10K 85/344: {comprising ruthenium}
- Y02E 10/542: Dye sensitized solar cells
- H10W: GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10)
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A functional device includes plural substrates, an encapsulant arranged between the plurality of substrates, and a functional material arranged between the plural of substrates and encapsulated with the encapsulant. The functional device further includes an insulating spacer arranged in an entire region where the encapsulant lies, wherein the insulating spacer bonds with the plural substrates through the encapsulant. The encapsulant and the insulating spacer of the functional device allow avoiding a short circuit by providing a constant separation distance between the plural substrates of the functional device and electrodes adjacent to the plural substrates. The insulating spacer is made of a material that is inert to the functional material.

## Claims

### Claim 1

A functional device comprising:
a plurality of substrates;
an electrode arranged on a first substrate of the plurality of substrates and a counter electrode arranged opposite to the electrode on a second substrate of the plurality of substrates; and
at least one enclosure structure arranged between the first substrate and the second substrate, wherein the at least one enclosure structure has a rectangular frame shape, wherein:
the at least one enclosure structure comprises at least three layers including a first encapsulant, a spacer, and a second encapsulant arranged vertically in this order,
in a first cross-section of the functional device, each of the first substrate of the plurality of substrates and the second substrate of the plurality of substrates directly bonds with two first separate portions of the at least one enclosure structure,
in a second cross-section of the functional device that is perpendicular to the first cross-section, each of the first substrate and the second substrate is separated from the at least one enclosure structure at two second separate portions of the at least one enclosure structure by at least one layer different from the at least one enclosure structure,
the spacer has a thickness that is equal to or less than a total thickness of the electrode and the counter electrode,
the functional device comprises a functional material arranged between the plurality of substrates and encapsulated with the at least one enclosure structure, wherein the functional material comprises a liquid composition, and
the spacer is inert to a solvent constituting the liquid composition and acts as a barrier to the solvent.

### Claim 2 (depends on 1)

The functional device according to claim 1, wherein the spacer comprises at least one material selected from inorganic materials, including glass, quartz, alumina, and zirconia, and organic materials, including polyethylenes, polypropylenes, poly(ethylene terephthalate)s, poly(ethylene naphthalate)s, poly(phenylene sulfide)s, and polyimides.

### Claim 3 (depends on 1)

The functional device according to claim 1, wherein the first encapsulant and the second encapsulant comprise at least one material selected from a group consisting of acrylic resins, epoxy resins, polyisobutylenes, urethane resins, silicone resins, ionomer resins, polyolefins, and glass frits.

### Claim 4 (depends on 1)

The functional device according to claim 1,
wherein the electrode and the counter electrode extend to edges of the plurality of substrates, respectively, and
wherein edges of the electrode and the counter electrode overlap each other at least partially so as to sandwich the at least one enclosure structure.

### Claim 5 (depends on 1)

The functional device according to claim 1, wherein the functional material comprises a liquid electrolyte composition, and wherein outer peripheries of the plurality of substrates are sealed.

### Claim 6 (depends on 5)

The functional device according to claim 5, wherein the functional device comprises a dye-sensitized solar cell.

### Claim 7 (depends on 1)

The functional device according to claim 1, wherein at least one of the first encapsulant and the second encapsulant is formed on a transparent conductive layer.

### Claim 8 (depends on 7)

The functional device according to claim 7, wherein a surface electrical resistance of the transparent conductive layer is equal to or less than 500 Ω/cm2.

### Claim 9 (depends on 1)

The functional device according to claim 1, wherein the spacer has a thickness that is equal to or less than a total thickness of a plurality of electrodes, wherein each electrode from the plurality of electrodes extends to an edge of a substrate from the plurality of substrates.

### Claim 10 (depends on 1)

The functional device according to claim 1, wherein the spacer has a rectangular cross-section.

### Claim 11 (depends on 1)

The functional device according to claim 1, wherein the electrode comprises a semiconductor particles layer and the counter electrode comprises a metal layer.

### Claim 12 (depends on 11)

The functional device according to claim 11, wherein the semiconductor particles layer comprises a plurality of particles of a first average diameter and a plurality of particles of a second average diameter, wherein the second average diameter is greater than the first average diameter.

### Claim 13 (depends on 11)

The functional device according to claim 11, wherein a surface area of the semiconductor particles layer is about 1000 times greater than a projected area of the semiconductor particles layer.

### Claim 14 (depends on 1)

The functional device according to claim 1, wherein at least one of the first encapsulant and the second encapsulant has a thickness between 0.1 μm and 50 μm.

### Claim 15

A functional device, comprising: a plurality of substrates; an electrode arranged on a first substrate of the plurality of substrates and a counter electrode arranged opposite to the electrode on a second substrate of the plurality of substrates; and
at least one enclosure structure arranged between the first substrate and the second substrate, wherein the at least one enclosure structure has a rectangular frame shape, wherein:
the at least one enclosure structure comprises at least three layers including a first encapsulant, a spacer, and a second encapsulant arranged vertically in this order,
in a first cross-section of the functional device, each of the first substrate of the plurality of substrates and the second substrate of the plurality of substrates directly bonds with at-least two first separate portions of the at least one enclosure structure,
in a second cross-section of the functional device that is perpendicular to the first cross-section, each of the first substrate and the second substrate is separated from the at least one enclosure structure at two second separate portions of the at least one enclosure structure by at least one layer different from the at least one enclosure structure,
the spacer has a thickness that is equal to or less than a total thickness of the electrode and the counter electrode,
the functional device comprises a functional material arranged between the plurality of substrates and encapsulated with the at least one enclosure structure, wherein the functional material comprises a liquid composition, and
the spacer is inert to a solvent constituting the liquid composition and acts as a barrier to the solvent.

### Claim 16 (depends on 15)

The functional device according to claim 15, wherein the electrode comprises a semiconductor particles layer comprising a plurality of particles of a first average diameter and a plurality of particles of a second average diameter, wherein the second average diameter is greater than the first average diameter.

### Claim 17 (depends on 15)

The functional device according to claim 15, wherein at least one of the first encapsulant and the second encapsulant has a thickness between 0.1 μm and 50 μm.

### Claim 18 (depends on 15)

The functional device according to claim 15, wherein the electrode comprises a semiconductor particles layer, and wherein a surface area of the semiconductor particles layer is about 1000 times greater than a projected area of the semiconductor particles layer.
