# US 8,146,348 B2 · Exhaust emission control device

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- Number: US 8,146,348 B2
- Document ID: US8146348B2
- Status: Granted
- Kind: B2
- Application number: 12/274,698
- Filed: 2008-11-20
- Published: 2009-05-21
- Granted: 2012-04-03
- Earliest claimed: 2007-11-21
- Assignees: Denso Corporation
- Inventors: Osamu Shimomura; Ataru Ichikawa
- Web page: https://patentgrep.com/patent/US8146348B2

## CPC

- F01N 3/035: with catalytic reactors
- F01N 3/208: {Control of selective catalytic reduction [SCR], e.g. by adjusting the dosing of reducing agent}
- F01N 13/009: {having two or more separate purifying devices arranged in series}
- F01N 2560/026: for measuring or detecting NOx
- F01N 2560/06: the means being a temperature sensor
- F01N 2610/146: Control thereof, e.g. control of injectors or injection valves
- F01N 2900/0408: using a feed-back loop
- F01N 2900/08: said parameters being related to the engine
- F01N 2900/1621: Catalyst conversion efficiency
- Y02T 10/12: Improving ICE efficiencies
- F01N: GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES (arrangements in connection with gas exhaust of propulsion units in vehicles B60K13/00; combustion-air intake silencers specially adapted for, or arranged on, internal-combustion engines F02M35/00; protecting against, or damping, noise in general G10K11/16)
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

An exhaust emission control device reduces nitrogen oxide in exhaust air from an engine. The device includes an exhaust pipe, a catalyst, a supply device, a NOx detecting device, and a control device. The pipe defines a passage for the exhaust air. The catalyst is disposed in the pipe and promotes reduction reaction of the nitrogen oxide. The supply device supplies an additive agent, which is used for the reaction, to an upstream side of the catalyst in the exhaust air flow direction. The detecting device detects the nitrogen oxide included in the exhaust airs which has passed through the catalyst. The control device controls the supply device. The control device determines a deterioration state of the catalyst based on a result detected by the detecting device and reduces an amount of the additive agent, which is supplied, according to the determined deterioration state.

## Claims

### Claim 1

An exhaust emission control device for reducing nitrogen oxide included in exhaust air from an internal combustion engine, the device comprising:
an exhaust pipe defining a passage for the exhaust air discharged from the engine;
a catalyst disposed in the exhaust pipe, the catalyst being capable of promoting reduction reaction of the nitrogen oxide in the exhaust air;
a supply unit for supplying an additive agent, which is used for the reduction reaction, to an upstream side of the catalyst in a flow direction of the exhaust air;
a NOx detecting unit for detecting the nitrogen oxide included in the exhaust air, which has passed through the catalyst;
a control unit having a program for controlling the supply unit, wherein the control unit determines a deterioration state of the catalyst based on a result detected by the NOx detecting unit and reduces an amount of the additive agent, which is supplied by the supply unit, in accordance with the determined deterioration state;
a rotational speed detecting unit for detecting a rotational speed of the engine;
a supply amount detecting unit for detecting an amount of fuel supplied to the engine;
a temperature detecting unit for detecting temperature of the exhaust air discharged from the engine; and
a memory unit for storing the result detected by the NOx detecting unit, wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit when at least one of the following conditions is satisfied and accordingly the engine is regarded as in continuous high-load operation:
the rotational speed of the engine is equal to or larger than a predetermined rotational speed;
the amount of fuel supplied to the engine is equal to or larger than a predetermined amount; and
the temperature of the exhaust air is equal to or larger than a predetermined temperature; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit when the engine is regarded as in continuous high-load operation, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 2 (depends on 1)

The exhaust emission control device according to claim 1, wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit when the rotational speed of the engine is equal to or smaller than a predetermined rotational speed and accordingly the engine is regarded as in idling operation; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit when the engine is regarded as in idling operation, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 3 (depends on 1)

The exhaust emission control device according to claim 1, further comprising:
a filter disposed on the upstream side of the catalyst in the flow direction of the exhaust air and configured to capture particles in the exhaust air; wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit while the filter is being recovered by heating the filter; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit while the filter is being recovered, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 4 (depends on 1)

The exhaust emission control device according to claim 1, further comprising:
an averaging unit for averaging a plurality of detection results obtained by the NOx detecting unit to output an averaged detection result; and
a memory unit for storing the averaged detection result obtained by the averaging unit, wherein when the averaged detection result is outputted by the averaging unit, the control unit determines the deterioration state of the catalyst by comparing the averaged detection result that is outputted, and the averaged detection result that has already been stored in the memory unit.

### Claim 5

An exhaust emission control device for reducing nitrogen oxide included in exhaust air from an internal combustion engine, the device comprising:
an exhaust pipe defining a passage for the exhaust air discharged from the engine;
a catalyst disposed in the exhaust pipe, the catalyst being capable of promoting reduction reaction of the nitrogen oxide in the exhaust air;
a supply unit for supplying an additive agent, which is used for the reduction reaction, to an upstream side of the catalyst in a flow direction of the exhaust air;
a NOx detecting unit for detecting the nitrogen oxide included in the exhaust air, which has passed through the catalyst;
a control unit having a program for controlling the supply unit, wherein the control unit determines a deterioration state of the catalyst based on a result detected by the NOx detecting unit and reduces an amount of the additive agent, which is supplied by the supply unit, in accordance with the determined deterioration state;
a rotational speed detecting unit for detecting a rotational speed of the engine; and
a memory unit for storing the result detected by the NOx detecting unit, wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit when the rotational speed of the engine is equal to or smaller than a predetermined rotational speed and accordingly the engine is regarded as in idling operation; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit when the engine is regarded as in idling operation, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 6 (depends on 5)

The exhaust emission control device according to claim 5, further comprising:
a supply amount detecting unit for detecting an amount of fuel supplied to the engine; and
a temperature detecting unit for detecting temperature of the exhaust air discharged from the engine; wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit when at least one of the following conditions is satisfied and accordingly the engine is regarded as in continuous high-load operation:
the rotational speed of the engine is equal to or larger than a predetermined rotational speed;
the amount of fuel supplied to the engine is equal to or larger than a predetermined amount; and
the temperature of the exhaust air is equal to or larger than a predetermined temperature; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit when the engine is regarded as in continuous high-load operation, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 7 (depends on 5)

The exhaust emission control device according to claim 5, further comprising:
a filter disposed on the upstream side of the catalyst in the flow direction of the exhaust air and configured to capture particles in the exhaust air; wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit while the filter is being recovered by heating the filter; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit while the filter is being recovered, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 8 (depends on 5)

The exhaust emission control device according to claim 5, further comprising:
an averaging unit for averaging a plurality of detection results obtained by the NOx detecting unit to output an averaged detection result; and
a memory unit for storing the averaged detection result obtained by the averaging unit, wherein when the averaged detection result is outputted by the averaging unit, the control unit determines the deterioration state of the catalyst by comparing the averaged detection result that is outputted, and the averaged detection result that has already been stored in the memory unit.

### Claim 9

An exhaust emission control device for reducing nitrogen oxide included in exhaust air from an internal combustion engine, the device comprising:
an exhaust pipe defining a passage for the exhaust air discharged from the engine;
a catalyst disposed in the exhaust pipe, the catalyst being capable of promoting reduction reaction of the nitrogen oxide in the exhaust air;
a supply unit for supplying an additive agent, which is used for the reduction reaction, to an upstream side of the catalyst in a flow direction of the exhaust air;
a NOx detecting unit for detecting the nitrogen oxide included in the exhaust air, which has passed through the catalyst;
a control unit having a program for controlling the supply unit, wherein the control unit determines a deterioration state of the catalyst based on a result detected by the NOx detecting unit and reduces an amount of the additive agent, which is supplied by the supply unit, in accordance with the determined deterioration state;
a filter disposed on the upstream side of the catalyst in the flow direction of the exhaust air and configured to capture particles in the exhaust air; and
a memory unit for storing the result detected by the NOx detecting unit, wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit while the filter is being recovered by heating the filter; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit while the filter is being recovered, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 10 (depends on 9)

The exhaust emission control device according to claim 9, further comprising:
a rotational speed detecting unit for detecting a rotational speed of the engine;
a supply amount detecting unit for detecting an amount of fuel supplied to the engine; and
a temperature detecting unit for detecting temperature of the exhaust air discharged from the engine; wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit when at least one of the following conditions is satisfied and accordingly the engine is regarded as in continuous high-load operation:
the rotational speed of the engine is equal to or larger than a predetermined rotational speed;
the amount of fuel supplied to the engine is equal to or larger than a predetermined amount; and
the temperature of the exhaust air is equal to or larger than a predetermined temperature; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit when the engine is regarded as in continuous high-load operation, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 11 (depends on 9)

The exhaust emission control device according to claim 9, further comprising:
a rotational speed detecting unit for detecting a rotational speed of the engine; wherein:
the control unit makes the memory unit store the result, which is detected by the NOx detecting unit when the rotational speed of the engine is equal to or smaller than a predetermined rotational speed and accordingly the engine is regarded as in idling operation; and
the control unit determines the deterioration state of the catalyst by comparing the result, which is detected by the NOx detecting unit when the engine is regarded as in idling operation, and the result detected by the NOx detecting unit and already stored in the memory unit.

### Claim 12 (depends on 9)

The exhaust emission control device according to claim 9, further comprising:
an averaging unit for averaging a plurality of detection results obtained by the NOx detecting unit to output an averaged detection result; and
a memory unit for storing the averaged detection result obtained by the averaging unit, wherein when the averaged detection result is outputted by the averaging unit, the control unit determines the deterioration state of the catalyst by comparing the averaged detection result that is outputted, and the averaged detection result that has already been stored in the memory unit.