Odorant mixture for odorless gas fuel
AssigneeArkema France
InventorPatrick Charles
Life of this patent
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Abstract
The invention concerns a composition for use in particular as odorant of a gas fuel, more particularly of natural gas, comprising: 0.1 to 49.9 particles by weight of at least one alkyl sulphur (I) of formula: R1—S—R2, wherein R1 and R2, identical or different, represent: an alkyl radical comprising 1 to 4 carbon atom; or R1 and R2 together with the sulfur atom to which they are bound represent a saturated or unsaturated ring including 3 to 5 carbon atoms, optionally substituted by a C1-C4 alkyl or C1-C4 alkenyl; 50 to 99.8 parts by weight of at least two alkyl acrylates (II) the alkyl radicals of which comprise 1 to 12 carbon atoms, preferably 1 to 8: 0.001 parts by weight of at least compound (III) inhibiting polymerization of the alkyl acrylates (II).
Claims16
Composition which can be used in particular as odorant for a gaseous fuel, more particularly natural gas, comprising:
- (a) from 5 to 14.95% of parts by weight of at least one alkyl sulphide (I) of formula:
- R1—S—R2
- in which R1 and R2, which are identical or different, and are selected from
- an alkyl radical comprising from 1 to 4 carbon atoms;
- or
- a saturated or unsaturated ring comprising from 3 to 5 carbon atoms when taken with the sulphur atom to which they are attached which ring is optionally substituted by a C1-C4 alkyl or C1-C4 alkenyl radical;
- (b) from 85 to 94.95% parts by weight of at least two alkyl acrylates (II), the alkyl radicals of which comprise from 1 to 12 carbon atoms;
- (c) from 0.005 to 0.05% part by weight of at least one compound (III) which inhibits the polymerization of the alkyl acrylates (II) in the absence of oxygen, consisting of a stable nitroxide radical of formula (IV):
- in which R3 and R4, which are identical or different, and are selected from
- a tertiary or secondary hydrocarbon radical comprising from 2 to 30 carbon atoms and optionally one or more heteroatoms chosen from sulphur, phosphorus, nitrogen or oxygen;
- or
- a cyclic hydrocarbon radical comprising from 4 to 10 carbon atoms taken with the nitrogen atom to which they are attached, said radical optionally being substituted.
Dependencies are inferred from the claim text.