2,7-carbazolenevinylene derivatives as novel materials in producing organic based electronic devices
AssigneeNational Research Council of Canada
InventorsNicolas Drolet, Jean-Francois Morin, Ye Tao, Mario Leclerc, Kathleen Sirois
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Abstract
Organic Field Effect Transistor (OFET), an Organic Light Emitting Diode (OLED), an and an Organic Photovoltaic Cell (OPC) including as active material a conjugated oligomeric or polymeric 2,7-carbazolenevinylene derivative described by the formula (I) or (II): Such OFETs, OLEDs and OPCs have improved devices properties and efficiencies.
Claims18
An organic based device which is an organic Field Effect Transistor (OFET) or an Organic Photovoltaic Cell (OPC), the device comprising as a first active material a conjugated oligomeric 2,7-carbazolenevinylene derivative described by the formula I:
- wherein X is a comonomer selected from the group consisting of ethylene, acetylene, a C6-C22 mononuclear/polynuclear aromatic group, a C2-C10 mononuclear/polynuclear heterocyclic group, and a tertiary arylamine, wherein A is selected from hydrogen, a linear or branched alkyl group containing 1 to 20 carbon atoms, a linear or branched alkoxy group containing 1 to 20 carbon atoms, a cyano group, a halogen group, a monovalent aromatic group, and a monovalent aromatic complex ring group having one nitrogen atom as a hetero-atom, wherein B is selected from hydrogen, a linear or branched alkyl group containing 1 to 20 carbon atoms, a linear or branched alkoxy group containing 1 to 20 carbon atoms, a cyano group, a halogen group, a monovalent aromatic group, and a monovalent aromatic complex ring group having one nitrogen atom as a hetero-atom, wherein R is selected from hydrogen, a linear or branched alkyl group containing 1 to 20 carbon atoms, a linear or branched alkoxy group containing 1 to 20 carbon atoms, a poly (ethyleneoxy) group, a cyano group, an aryl group, an amide group, and a benzoyl group, and where n is an integer equal to 1 or 2.
An organic based device which is, an organic Field Effect Transistor (OFET) or an Organic Photovoltaic Cell (OPC), the device comprising as a first active material a polymer of monomers defined by Formula II:
- and optionally of a second comonomer which is one of ethylene, acetylene, a C6-C22 mononuclear/polynuclear aromatic group, a C2-C10 mononuclear/polynuclear heterocyclic group, and a tertiary arylamine,
- wherein R is selected from hydrogen, a linear or branched alkyl group containing 1 to 20 carbon atoms, a linear or branched alkoxy group containing 1 to 20 carbon atoms, a poly (ethyleneoxy) group, a cyano group, an aryl group, an amide group, and a benzoyl group, the polymer having a first end-cap group selected from hydrogen, a linear or branched alkyl group containing 1 to 20 carbon atoms, a linear or branched alkoxy group containing 1 to 20 carbon atoms, a cyano group, a halogen group, a monovalent aromatic group, and a monovalent aromatic complex ring group having one nitrogen atom as a hetero-atom,
- and the polymer having a second end-cap group selected from hydrogen, a linear or branched alkyl group containing 1 to 20 carbon atoms, a linear or branched alkoxy group containing 1 to 20 carbon atoms, a cyano group, a halogen group, a monovalent aromatic group, and a monovalent aromatic complex ring group having one nitrogen atom as a hetero-atom.
Dependencies are inferred from the claim text.