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US 8,134,037 B2Granted
Xylene isomerization process and apparatus
AssigneeUop LLC
InventorsPaula L. Bogdan, Robert B. Larson, James E. Rekoske, Patrick J. Silady, Patrick C. Whitchurch, Freddie Sandifer
Life of this patent
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Abstract
Xylene isomerization processes, especially those processes in which ethylbenzene is also converted, are beneficially affected by adding benzene to the feed.
Claims9
A process for the isomerization of a non-equilibrium feed mixture of xylenes comprising:
- adding to the feed mixture, a stream consisting essentially of benzene to provide a feed stream;
- contacting in the presence of hydrogen the feed stream with a catalyst selected from the group consisting of:
- a) a catalyst comprising a 46 micron to 60 micron active layer of MFI zeolite and zirconia or titania on an inert alpha alumina core and the catalyst further comprising a hydrogenation component selected from the group consisting of platinum, palladium, molybdenum, and rhenium;
- b) a catalyst comprising a MFI zeolite and silica support and a hydrogenation component selected from the group consisting of platinum, palladium, molybdenum, and rhenium;
- and
- c) mixtures thereof,
- under isomerization conditions to isomerize the xylenes and provide a product stream having a redistributed xylenes ratio, wherein the stream consisting essentially of benzene is added in an amount resulting in the feed stream comprising from about 0.5 to about 25 mass percent benzene.
4 more elements
Dependencies are inferred from the claim text.