Hydrogenolytic denitration of polynitro compounds: pentanitrohexaazaisowurtzitane
AssigneeThe United States of America as represented by the Secretary of the Army
InventorsRaja Duddu, Paritosh Dave, Reddy Damavarapu, Rao Surapaneni
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Abstract
A method for synthesizing pentanitrohexaazaisowurtzintane under neutral reaction conditions. Which synthesis involves treating a solution of hexanitrohexaazaisowurtzitane in ethyl acetate in the presence of a catalytic quantity of palladium on a carbon substrate, until a heterogeneous mixture is formed. This heterogeneous mixture is hydrogenated under a balloon atmosphere until the starting hexanitrohexaazaisowurtzitane is substantially reacted. The resulting pentanitrohexaazaisowurzitane mixture is filtered, dried and recovered from the dried residue through a Si-gel column.
Claims1
A method for preparing pentanitrohexaazaisowurzitane under neutral reaction conditions, said method comprising the steps of:
- a) treating a solution of hexanitrohexaazaisowurtzitane (2.11 mmol) in ethyl acetate with 10% Pd—C (100 mg) resulting in a heterogeneous mixture;
- b) subjecting the heterogeneous mixture to hydrogenation under balloon atmosphere while monitoring the progress of the reaction by thin layer chromatography;
- c) filtering the resulting reaction mixture and evaporating it to dryness;
- and
- d) recovering the pentanitrohexaazaisowurzitane from the dry residue by passing the residue through a Si-gel column.
Dependencies are inferred from the claim text.