Multiple catalyst system for olefin polymerization and polymers produced therefrom

An olefin polymer comprising C2 to C20 olefins where the polymer is the reaction product resulting from the continuous process of combining under polymerization conditions:

• (A) a first catalyst capable of producing a first crystalline polymer having an Mw of 100,000 or less, the first catalyst having the formula
• wherein
• A′ is a bridging group,
• M is zirconium, hafnium or titanium,
• X1 and X2 are, independently, hydride radicals, hydrocarbyl radicals, substituted hydrocarbyl radicals, halocarbyl radicals, substituted halocarbyl radicals, and hydrocarbyl- and halocarbyl-substituted organometalloid radicals, halogen, alkoxide, aryloxide, amide, or phosphide,
• S″v are, independently, a radical group which is a hydrocarbyl, substituted-hydrocarbyl, halocarbyl, substituted-halocarbyl, hydrocarbyl-substituted organometalloid, halocarbyl-substituted organometalloid, disubstituted boron, halogen radicals, or form a C4 to C20 ring to give a saturated or unsaturated polycyclic cyclopentadienyl ligand where the subscript “v” denotes the carbon atom on the Cp-ring to which the substituent is bonded;
• (B) a second catalyst capable of preparing a second amorphous polymer having an Mw of 100,000 or less and differing in chemical or physical properties from the first polymer under equivalent polymerization conditions,
• (C) a cocatalyst, activator, scavenger, or combination thereof, and
• (D) one or more olefins;
• wherein the polymer is formed in-situ, comprises crystalline polymer segments and amorphous polymer segments, and has an Mw of 100,000 or less.