Insecticides

A compound of formula I

• wherein
• or D is a group
• R4, R4′, R10, R17, and R19 independently from each other, are hydrogen, C1-C6alkyl, C3-C6cycloalkyl, C1-C6haloalkyl, halogen, cyano, C1-C4alkoxy, C1-C4haloalkoxy, C2-C4alkoxycarbonyl, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4haloalkylsulfinyl or C1-C4haloalkylsulfonyl;
• R5, R6, R8, R11, R12, R15, R16 and R18 independently from each other, are C1-C6alkyl, or C1-C6alkyl mono-, di- or trisubstituted by halogen, cyano, nitro, hydroxy, C1-C4alkoxy, C2-C4alkoxycarbonyl, C1-C4alkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylamino, C2-C4dialkylamino or C3-C6cycloalkylamino;
• or are phenyl, 2-pyridyl, 3-pyridyl, 4-pyridyl;
• or are phenyl, 2-pyridyl, 3-pyridyl or 4-pyridyl mono-, di- or trisubstituted by C1-C6alkyl, C3-C6cycloalkyl, C1-C6haloalkyl, halogen, cyano, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4haloalkylsulfinyl or C1-C4haloalkylsulfonyl;
• R7, R9, R13 and R14 independently from each other, are hydrogen, C1-C6alkyl, C1-C6haloalkyl, C2-C6alkenyl, C2-C6haloalkenyl, C3-C6alkenyl or C3-C6haloalkenyl;
• each R1 independently is halogen, nitro, cyano, hydroxy, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C3-C6cycloalkyl, C1-C6haloalkyl, C2-C6haloalkenyl, C2-C6haloalkynyl, C3-C6halocycloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylamino, C2-C4dialkylamino, C3-C6cycloalkylamino, C1-C6alkyl-C3-C6cycloalkylamino, C2-C4alkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6alkylaminocarbonyl, C3-C6dialkylaminocarbonyl, C2-C6alkoxycarbonyloxy, C2-C6alkylaminocarbonyloxy, C3-C6dialkylaminocarbonyloxy or C3-C6-trialkylsilyl, phenyl, benzyl or phenoxy, or phenyl, benzyl or phenoxy mono-, di- or trisubstituted by halogen, cyano, nitro, halogen, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C3-C6cycloalkyl, C1-C6haloalkyl, C2-C6haloalkenyl, C2-C6haloalkynyl, C3-C6halocycloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylamino, C2-C4dialkylamino, C3-C6cycloalkylamino, C1-C6alkyl-C3-C6cycloalkylamino, C2-C4alkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6alkylaminocarbonyl, C3-C6dialkylaminocarbonyl, C2-C6alkoxycarbonyloxy, C2-C6alkylaminocarbonyloxy, C3-C6dialkylaminocarbonyloxy or C3-C6-trialkylsilyl;
• n is 0, 1, 2 or 3;
• each of R2 and R3, which may be the same or different, represents hydrogen, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl or C3-C8cycloalkyl;
• or C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl or C3-C8cycloalkyl substituted by one or more substituents selected from halogen nitro, cyano, hydroxy, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylamino, C2-C4dialkylamino, C3-C6cycloalkylamino and C1-C6alkyl-C3-C6cycloalkylamino;
• each of E1 and E2, which may be the same or different, represents oxygen or sulfur;
• A is oxygen, sulfur, SO, SO2, S(O)p═N—R, C═N—OR36, N—R0, C═O or P(X)t—R33;
• R33 is hydrogen, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C1-C6haloalkyl, C1-C6alkoxy, hydroxy, C3-C6cycloalkyl, C3-C6cycloalkyl-C1-C6alkyl, benzyl or phenyl;
• where phenyl and benzyl for their part may be mono- di- or trisubstituted by C1-C6alkyl, C1-C6haloalkyl, halogen, cyano or nitro;
• or R33 is O−Na+, O−Li+ or O−K+;
• R36 is hydrogen, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C1-C6haloalkyl, C2-C6haloalkenyl, C2-C6haloalkynyl, C1-C6alkoxy-C1-C6alkyl, C1-C6haloalkoxy-C1-C6alkyl or benzyl;
• X is oxygen or sulfur;
• p is 0 or 1;
• t is 0 or 1;
• each of R34 and R35, which may be the same or different, represents hydrogen, COOH, halogen, nitro, cyano, hydroxy, C1-C6alkyl, C1-C6haloalkyl, C2-C6alkenyl, C2-C6alkynyl, C2-C6haloalkenyl, C2-C6haloalkynyl, C1-C6alkylthio, C1-C6alkylsulfinyl, C1-C6alkylsulfonyl, C1-C6haloalkylthio, C1-C6haloalkylsulfinyl, C1-C6haloalkylsulfonyl, C1-C6alkoxycarbonyl, C1-C6alkylcarbonyl, C3-C6alkylaminocarbonyl, C3-C6dialkylaminocarbonyl, C1-C6alkoxy-C1-C6alkyl, C1-C6haloalkoxy-C1-C6alkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylamino, C2-C6dialkylamino, C3-C6-trialkylsilyl, benzyl or phenyl;
• where phenyl and benzyl for their part may be mono- di- or trisubstituted by C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, halogen, cyano, hydroxyl or nitro;
• m is 0, 1, 2, 3 or 4;
• R is hydrogen, C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkoxy-C1-C6alkyl or C1-C6haloalkoxy-C1-C6alkyl;
• or R is C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkoxy-C1-C6alkyl or C1-C6haloalkoxy-C1-C6alkyl substituted by C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkoxy, or C1-C6haloalkoxy;
• or R is cyano, nitro, —C(O)R26, —C(O)OR27, —CONR28R29, SO2R30 or —P(O)(OR31)(OR32);
• R0 is hydrogen, C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkoxy-C1-C6alkyl or C1-C6haloalkoxy-C1-C6alkyl;
• or R0 is C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkoxy-C1-C6alkyl or C1-C6haloalkoxy-C1-C6alkyl substituted by C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkoxy, or C1-C6haloalkoxy;
• or R0 is cyano, nitro, —C(O)R026, —C(O)OR027, —CONR028R029, —SO2R030 or —P(O)(OR031)(OR032);
• or R0 is phenyl or benzyl, or phenyl or benzyl mono-, di- or trisubstituted by substituents selected from C1-C6alkyl, C3-C6cycloalkyl, C1-C6haloalkyl, halogen, cyano, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4haloalkylsulfinyl and C1-C4haloalkylsulfonyl;
• each of R26 and R026, which may be the same or different, represents hydrogen, C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkoxycarbonyl, C1-C6alkylcarbonyl or C1-C6alkoxy-C1-C6alkyl;
• or C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkoxycarbonyl, C1-C6alkylcarbonyl or C1-C6alkoxy-C1-C6alkyl substituted by C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkoxy, or C1-C6haloalkoxy;
• each of R27, R28, R29, R30, R31, R32, R027, R028, R029, R030, R031 and R032 which may be the same or different, represents C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl or C3-C6halocycloalkyl;
• or C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl or C3-C6halocycloalkyl substituted by C1-C6alkyl, C1-C6haloalkyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkoxy or C1-C6haloalkoxy;
• with the proviso that E1 or E2 is sulfur if A is oxygen, sulfur or N—R0, wherein R0 is hydrogen, C1-C3alkyl, C1-C3haloalkyl, C2-C4alkylcarbonyl, C2-C4haloalkylcarbonyl, C2-C4alkoxycarbonyl or C1-C3alkylsulfonyl;
• and agronomically acceptable salts/isomers/diastereomers/enantiomers/tautomers/N-oxides of those compounds said compound.