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US 8,076,000 B2Granted
Tie-layer materials for use with ionomer-based films and sheets as skins on other materials
AssigneeExxonMobil Chemical Patents Inc.
InventorJoseph Dominic Domine
Life of this patent
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Abstract
The present invention relates to new combinations of tie-layers and backing layers and/or substrates for making (1) new multilayer structures formed from one or more ionomers and one or more tie-layers, and optionally a backing layer to form laminates, (2) new composite articles made from these laminates in combination with optional substrate materials, and (3) new methods of making composite articles from these laminates by shaping and subsequently contacting them with a substrate material.
Claims17
A laminate comprising:
- an ionomer layer, wherein the ionomer layer comprises a first ionomer layer and a second ionomer layer and wherein one or both of the first ionomer layer and the second ionomer layer is pigmented, natural color, or clear, wherein the first ionomer layer comprises a blend of:
- (a) 45 to 95 wt % of a first ionomer having a melt index (MI190/2.16) of from 0.6 to 1.0 dg/min;
- and (b) a second ionomer having a melt index (MI190/2.16) of from 2.1 to 3.0 dg/min and the first ionomer has a different metallation than the second ionomer;
- a tie layer comprising at least one coextrudable tie resin selected from an epoxy containing copolymer and a copolymer of one or more C2-C10 α-olefin and one or more ethylenically copolymerizable amine-containing monomer of the general formula:
- wherein each R is independently H or a C1 to C10 hydrocarbon and R′ is a bond or a C1 to C10 hydrocarbon, and wherein the coextrudable tie resin has a melt index (MI190/2.16) of about 2.0 to about 10 dg/min;
- and
- a backing layer comprising a blend of said at least one coextrudable tie resin and at least one of a polyamide polymer, a polyamide compound, a polyamide elastomer, an acrylic polymer, an elastomer, a styrenic polymer, a copolymer containing cyclic monomer(s), a polyurethane polymer, or mixtures thereof;
- wherein the tie-layer is disposed between the ionomer layer and the backing layer.
5 more elements
Dependencies are inferred from the claim text.