Dichromophore carbonyl or heterocyclic dye, dye composition comprising this dye, process for dyeing keratin materials using this dye
AssigneeL'oreal
InventorAndrew Greaves
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Abstract
The invention relates to the dyeing of keratin materials using dichromophore dyes with a carbonyl or heterocyclic linker. The invention relates to a dye composition comprising a dye with a carbonyl or heterocyclic linker, and to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers such as the hair, using said composition, optionally in the presence of a cosmetically acceptable acid or base. It similarly relates to novel dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.
Claims17
A dye of formula (I):
- A-(L)p-Csat—S—Y-(L′)p′-Y—S—Csat-(L)p-A (I)
- the organic or mineral acid salts, optical isomers and geometric isomers thereof, and the solvates such as hydrates:
- in which formula (I):
- A represents a radical containing at least one chromophore which is optionally cationic, colored, or colored and fluorescent;
- L and L′, which may be identical or different, represent:
- a saturated or unsaturated, linear or branched C1-C20 hydrocarbon-based chain which is optionally substituted, optionally interrupted and/or optionally terminated at one or both of its ends with one or more divalent groups or combinations thereof chosen from —N(R)—, —O—, —S—, —C(O)— and —SO2—, with R, R′, which may be identical or different, being chosen from a hydrogen, and a C1-C4 alkyl, hydroxyalkyl and aminoalkyl radical;
- it being understood that said combination cannot form a disulfide bond —S—S—;
- an arylene group,
- a heteroarylene group,
- a cycloalkylene group, or
- a heterocycloalkylene group;
- Y represents a carbonyl group or a heteroaryl group, which is cationic or noncationic, which comprises 5-13 members, which is optionally substituted, and which comprises from 1 to 5 heteroatoms chosen from oxygen, sulfur, or nitrogen atoms;
- p and p′, which may be identical or different, represent an integer equal to 0 or 1;
- and
- Csat represents an optionally substituted, linear or branched C1-C18 alkylene chain.
The dye of formula (I) as claimed in the preceding claim, in which the chromophore A represents:
- W—N═N—Ar—Z— or Ar—N═N—W—
- with:
- W representing a heteroaryl, comprising a quaternary ammonium, optionally substituted preferably with one or more (C1-C4) alkyl groups;
- Ar representing i) a 5- or 6-membered (hetero)aryl radical of phenyl or pyridium type, or ii) a (hetero) aromatic bicycle of naphthyl, benzopyridinyl, indolinyl or benzoindolinyl type, optionally substituted with one or more halogen atoms, with one or more alkyl groups, with one or more hydroxyl groups, with one or more alkoxy groups, with one or more hydroxyalkyl groups, with one or more amino or (di)alkylamino groups;
- and
- Z representing an oxygen or sulfur atom, or a group NR′ with R′ representing a (hydroxy)(C1-C4) alkyl group.
Dependencies are inferred from the claim text.