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US 8,066,782 B2Granted
Azomethine direct dyes or reduced precursors of azomethine direct dyes obtained from 2-alkylresorcinols, and hair dyeing process using these dyes or precursors
AssigneeL'oreal
InventorsMadeleine Leduc, Eric Metais, Stéphane Sabelle, Christophe Rondot
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Abstract
The invention relates to the dyeing of keratin fibres using azomethine direct dyes or precursors of azomethine dyes obtained from 2-alkylresorcinols. The invention relates to a dye composition comprising at least one azomethine direct dye or pre-cursor of an azomethine direct dye, to a process for dyeing keratin fibres, using the said composition, and to their uses in the dyeing of keratin fibres. This composition allows a particularly stable and fast coloration to be obtained.
Claims19
A compound of formula (I) or (II):
- the salts thereof with an organic or mineral acid, geometrical isomers thereof, tautomers thereof, and solvates thereof including hydrates;
- in which formula (I) or (II):
- R1, which may be identical or different, represent:
- a chlorine atom;
- a (C1-C3) alkyl radical optionally substituted with one or more hydroxyl groups;
- a (C1-C3) alkoxy radical optionally substituted with one or more hydroxyl groups;
- R2 represents a (C1-C3) alkyl radical;
- X, which may be identical or different, represent:
- a hydroxyl radical;
- a radical —NR3R4 with R3 and R4 representing, independently of each other:
- i) a hydrogen atom;
- ii) a C1-C5 alkyl radical optionally substituted with one or more groups chosen from hydroxyl, (C1-C3)alkoxy, amino, (C1-C3)alkylamino, di(C1-C3) alkylamino, amino-carbonyl, carboxylic —COOH, sulfonic —SO3H, tri(C1-C3) alkylammonium and (C1-C3)alkyl-imidazolium;
- a pyrrolidinyl radical optionally substituted with a group chosen from hydroxyl, (C1-C3)alkoxy, amino, (C1-C3)alkylamino, di (C1-C3)alkylamino, tri(C1-C3)alkylammonium and (C1-C3) alkylimidazolium;
- a piperidine radical optionally substituted with a group chosen from hydroxyl, (C1-C3)alkoxy, amino, (C1-C3)alkylamino, di(C1-C3)alkylamino, tri(C1-C3)alkylammonium and (C1-C3)alkylimid-azolium and;
- n represents an integer between 0 and 3 inclusive;
- with the proviso that when X and/or R3 and/or R4 comprise a cationic group, the electrical neutrality of the compound of formula (I) or (II) is achieved with an anionic counterion or a mixture of anionic counterions that are cosmetically acceptable, including chlorides, bromides and sulfates.
13 more elements
Dependencies are inferred from the claim text.