Zwitterionic Group VIII transition metal initiators supported by olefin ligands
AssigneeThe Regents of the University of California
InventorsGuillermo C. Bazan, Yaofeng Chen
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Abstract
A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.
Claims11
A zwitterionic Group VIII transition metal complex containing a 3-(arylimino)-but-1-en-2-olato ligand.
A process for polymerization or copolymerization of an olefin, comprising:
- conducting the polymerization in the presence of a zwitterionic Group VIII transition metal complex containing a 3-(arylimino)-but-1-en-2-olato ligand.
Dependencies are inferred from the claim text.