Cross-linkable fluoroelastomer, its composition and cross-linked rubber molded product
AssigneeAsahi Glass Company, Limited
InventorsMasahide Yodogawa, Masayuki Saito
Life of this patent
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Abstract
To provide a cross-linkable fluoroelastomer, a cross-linkable fluoroelastomer composition and a cross-linked rubber molded products thereof. A cross-linkable fluoroelastomer having a Mooney viscosity of from 20 to 300, obtainable by heat treating a mixture of a fluoroelastomer (A) and an organic peroxide (B) at a temperature of from 110 to 380° C. for from 10 seconds to 3 hours; a fluoroelastomer composition comprising the cross-linkable fluoroelastomer, a cross-linking agent (C) and a cross-linking assistant (D); and cross-linked rubber molded products thereof.
Claims42
A cross-linkable fluoroelastomer having a Mooney viscosity of from 20 to 300, obtained by heat treating a mixture of a fluoroelastomer (A) and an organic peroxide (B) at a temperature of from 110 to 380° C. for from 10 seconds to 3 hours,
- wherein the cross-linkable fluoroelastomer has an absorption peak at from 1,640 to 1,700 cm−1, wherein the intensity of the absorption peak at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum as represented by absorbance of a hot pressed sample having a thickness of 0.2 mm is from 0.05 to 1.5, and
- wherein after the heat treating the cross-linkable fluoroelastomer has more unsaturated carbon-carbon bonds than the fluoroelastomer (A),
- wherein the fluoroelastomer (A) is a tetrafluoroethylene/propylene copolymer.
A method for producing a cross-linkable fluoroelastomer, which comprises
- heat-treating a mixture of a fluoroelastomer (A) and an organic peroxide (B) at a temperature of from 110 to 380° C. for from 10 seconds to 3 hours to form the cross-linkable fluoroelastomer,
- wherein the cross-linkable fluoroelastomer formed by the heat-treating has an absorption peak at from 1,640 to 1,700 cm−1, wherein the intensity of the absorption peak at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum as represented by absorbance of a hot pressed sample having a thickness of 0.2 mm is from 0.05 to 1.5, and
- wherein after the heat treating the cross-linkable fluoroelastomer has more unsaturated carbon-carbon bonds than the fluoroelastomer (A),
- wherein the fluoroelastomer (A) is a tetrafluoroethylene/propylene copolymer.
A cross-linkable fluoroelastomer obtained by a heat-treatment of a mixture of a fluoroelastomer (A) which does not have an absorption peak at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum, and an organic peroxide (B) at a temperature of from 110 to 380° C. for from 10 seconds to 3 hours, wherein the cross-linkable fluoroelastomer has a Mooney viscosity of from 20 to 300, of which the absorption peak is at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum;
- the intensity of the absorption peak at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum as represented by absorbance of a hot pressed sample having a thickness of 0.2 mm is from 0.05 to 1.5;
- and the infrared absorption spectrum as represented by absorbance has no absorption peak at from 1,740 to 1,800 cm−1 or has an absorption peak at from 1,740 to 1,800 cm−1 with an absorption peak intensity of at most 0.2, and
- wherein after the heat treating the cross-linkable fluoroelastomer has more unsaturated carbon-carbon bonds than the fluoroelastomer (A),
- wherein the fluoroelastomer (A) is a tetrafluoroethylene/propylene copolymer.
A process for producing a cross-linkable fluoroelastomer comprising a heat-treatment of a mixture of a fluoroelastomer (A) which does not have an absorption peak at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum, and an organic peroxide (B) at a temperature of from 110 to 380° C. for from 10 seconds to 3 hours,
- wherein the cross-linkable fluoroelastomer has a Mooney viscosity of from 20 to 300, of which the absorption peak is at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum;
- the intensity of the absorption peak at from 1,640 to 1,700 cm−1 of the infrared absorption spectrum as represented by absorbance of a hot pressed sample having a thickness of 0.2 mm is from 0.05 to 1.5;
- and the infrared absorption spectrum as represented by absorbance has no absorption peak at from 1,740 to 1,800 cm−1 or has an absorption peak, at from 1,740 to 1,800 cm−1 with an absorption peak intensity of at most 0.2, and
- wherein after the heat treating the cross-linkable fluoroelastomer has more unsaturated carbon-carbon bonds than the fluoroelastomer (A),
- wherein the fluoroelastomer (A) is a tetrafluoroethylene/propylene copolymer.
Dependencies are inferred from the claim text.