Inorganic mixed oxide and catalyst for purification of exhaust gas using the same
AssigneesKabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Cataler Corporation
InventorsMiho Hatanaka, Toshitaka Tanabe, Naoki Takahashi, Takeru Yoshida, Yuki Aoki
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Abstract
A particulate inorganic mixed oxide comprising: aluminum; zirconium; cerium; lanthanum and an additional element selected from the group consisting of neodymium and praseodymium, wherein the inorganic mixed oxide has at least 80% of primary particles with article diameters of 100 nm or less, and at least a part of the primary particles have an enriched surface region where the additional element is locally increased in a surface layer portion thereof.
Claims6
A particulate inorganic mixed oxide comprising:
- aluminum;
- zirconium;
- cerium;
- lanthanum;
- and
- an additional element selected from the group consisting of neodymium and praseodymium, wherein
- a content of aluminum in the inorganic mixed oxide is 60 to 90 at %, in terms of element content, relative to a total amount of elements which form cations in the inorganic mixed oxide,
- a content of cerium in the inorganic mixed oxide is 0.4 to 50 at %, in terms of element content, relative to a total amount of zirconium and cerium in the inorganic mixed oxide,
- a content of a total amount of lanthanum and the additional element is 1 to 12 at %, in terms of element content, relative to the total amount of the elements which form cations in the inorganic mixed oxide,
- at least 80% of primary particles of the inorganic mixed oxide have a particle diameter of 100 nm or less,
- at least a part of the primary particles have an enriched surface region where a content of the additional element is locally increased in a surface layer portion thereof, and
- an amount of the additional element in the enriched surface region is 0.1 to 0.95% by mass, in terms of oxide, relative to a whole amount of the inorganic mixed oxide.
Dependencies are inferred from the claim text.