Polymer compounds and a preparation method thereof

A co-polymer compound comprising at least one repeating unit represented by the following Formulae in Group A and at least one repeating unit represented by the following Formulae in Group B:

• Group A:
• Group B:
• wherein Ar1 is a tetravalent C5-C24 arylene group or a tetravalent C5-C24 heterocyclic ring, which is substituted or unsubstituted with at least one substituent selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, C1-C10 haloalkyl and C1-C10 haloalkoxy, or two or more of which are fused together to form a condensation ring or covalently bonded to each other via a functional group selected from the group consisting of O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2 and C(═O)NH;
• Ar1′ and Ar2 are identical to or different from each other and are each independently a bivalent C5-C24 arylene group or a bivalent C5-C24 heterocyclic ring, which is substituted or unsubstituted with at least one substituent selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, haloalkyl and C1-C10 haloalkoxy, or two or more of which are fused together to form a condensation ring or covalently bonded to each other via a functional group selected from the group consisting of O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2 , and C(═O)NH;
• Q is O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2, C(═O)NH, C(CH3)(CF3), C1-C6 alkyl-substituted phenyl or C1-C6 haloalkyl-substituted phenyl in which Q is linked to opposite both phenyl rings in the position of m-m, m-p, p-m or p-p;
• Y″ is —O or S;
• n is an integer from 10 to 400;
• and
• 1 is an integer from 10 to 400;
• wherein the co-polymer compound is treated by an acidic dopant.

A co-polymer compound comprising at least one repeating unit represented by the following Formulae in Group A and at least one repeating unit represented by the following Formulae in Group B:

• Group A:
• Group B:
• wherein Ar1 is a tetravalent C5-C24 arylene group or a tetravalent C5-C24 heterocyclic ring, which is substituted or unsubstituted with at least one substituent selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, C1-C10 haloalkyl and C1-C10 haloalkoxy, or two or more of which are fused together to form a condensation ring or covalently bonded to each other via a functional group selected from the group consisting of O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2 and C(═O)NH;
• Ar1′ and Ar2 are identical to or different from each other and are each independently a bivalent C5-C24 arylene group or a bivalent C5-C24 heterocyclic ring, which is substituted or unsubstituted with at least one substituent selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, C1-C10 haloalkyl and C1-C10 haloalkoxy, or two or more of which are fused together to form a condensation ring or covalently bonded to each other via a functional group selected from the group consisting of O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2 and C(═O)NH;
• Q is O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p ( in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2, C(═O)NH, C(CH3)(CF3), C1-C6 alkyl-substituted phenyl or C1-C6 haloalkyl-substituted phenyl in which Q is linked to opposite both phenyl rings in the position of m-m, m-p, p-m or p-p;
• Y″ is —O or S;
• n is an integer from 10 to 400;
• and
• 1 is an integer from 10 to 400;
• wherein the co-polymer compound includes inorganic filler selected from the group consisting of phosphotungstic acid (PWA), phosphomolybdenic acid, silicotungstic acid (SiWA), molybdophosphoric acid, silicomolybdic acid, phosphotin acid, zirconium phosphate (ZrP) and mixtures thereof.

A method for preparing a co-polymer compound comprising:

• thermally treating co-polymer units comprising at least one repeating unit represented by the following Formulae in Group C and at least one repeating unit represented by the following Formulae in Group D:
• Group C:
• Group D:
• wherein Ar1 is a tetravalent C5-C24 arylene group or a tetravalent C5-C24 heterocyclic ring, which is substituted or unsubstituted with at least one substituent selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, C1-C10 haloalkyl and C1-C10 haloalkoxy, or two or more of which are fused together to form a condensation ring or covalently bonded to each other via a functional group selected from the group consisting of O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2 and C(═O)NH;
• Ar2 is a bivalent C5-C24 arylene group or a bivalent C5-C24 heterocyclic ring, which is substituted or unsubstituted with at least one substituent selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, C1-C10 haloalkyl and C1-C10 haloalkoxy, or two or more of which are fused together to form a condensation ring or covalently bonded to each other via a functional group selected from the group consisting of O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10), C(CH3)2, C(CF3)2 and C(═O)NH;
• Q is O, S, C(═O), CH(OH), S(═O)2, Si(CH3)2, (CH2)p (in which 1≦p≦10), (CF2)q (in which 1≦q≦10) C(CH3)2, C(CF3)2, C(═O)NH, C(CH3)(CF3), C1-C6 alkyl-substituted phenyl or C1-C6 haloalkyl-substituted phenyl in which Q is linked to opposite both phenyl rings in the position of m-m, m-p, p-m or p-p;
• Y is —OH or —SH;
• Y′ is different from Y and is —OH or —SH;
• n is an integer from 10 to 400;
• and
• 1 is an integer from 10 to 400.