Recycling of ionic liquid catalyst
AssigneeChevron U.S.A. Inc.
InventorSven Ivar Hommeltoft
Life of this patent
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Abstract
Provided is a process for safely transporting or recycling an ionic liquid catalyst based on chloroaluminates. The process comprises mixing a secondary alcohol with an ionic liquid based on a chloroaluminate and allowing a reaction to occur forming an aluminum chloride adduct precipitate. The precipitate is filtered and the secondary alcohol removed, leaving a solid salt. This solid salt is the ionic liquid catalyst absent aluminum chloride, for example, Nbutylpyridinium chloride. This salt is recycled to the reactor. AlCl3 is added to the salt prior to introduction into the reactor to remake the ionic liquid catalyst, for example, Nbutylpyridinium heptachloroaluminate.
Claims26
A process for preparing a salt of an ionic liquid based on a chloroaluminate comprising:
- mixing an ionic liquid based on a chloroaluminate with a secondary alcohol and forming an aluminum chloride adduct precipitate;
- removing the precipitate;
- and
- removing the secondary alcohol to thereby leave a halide salt of the ionic liquid.
A method of transporting an ionic liquid based on a chloroaluminate comprising:
- mixing an ionic liquid based on a chloroaluminate with a secondary alcohol and forming an aluminum chloride adduct precipitate;
- removing the precipitate,
- removing the secondary alcohol to thereby leave a halide salt of the ionic liquid, and transporting the halide salt to a selected destination.
Dependencies are inferred from the claim text.