Multi-layer, microporous membrane, battery separator and battery
AssigneeToray Tonen Specialty Separator Godo Kaisha
InventorsKoichi Kono, Kohtaro Kimishima, Hiroyuki Ozaki, Patrick Brant, Jeffrey L. Brinen, Zerong Lin
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Abstract
The invention relates to a multi-layer, microporous polyolefin membrane having appropriate permeability, pin puncture strength, shutdown temperature, shutdown speed, meltdown temperature, and thickness uniformity. The invention also relates to a battery separator formed by such multi-layer, microporous membrane, and a battery comprising such a separator. Another aspect of the invention relates to a method for making the multi-layer, microporous polyolefin membrane, a method for making a battery using such a membrane as a separator, and a method for using such a battery.
Claims12
A three-layer microporous membrane, comprising:
- a first microporous layer containing a first layer material, a third microporous layer containing the first layer material, and a second microporous layer containing a second layer material, the second microporous layer being located between the first and third microporous layers,
- wherein the first layer material comprises a first polyethylene and a first polypropylene and the second layer material comprises a second polyethylene and a second polypropylene, the second polypropylene having (1) a weight-average molecular weight of 6×105 or more, (2) a heat of fusion of 90 J/g or more, and (3) a fraction having a molecular weight of 5×104 or less with the fraction being 5% or less by mass of the second polypropylene, and
- the first polyethylene is present in the first layer material in a first polyethylene amount in the range of from about 50 wt. % to about 99 wt. % based on the weight of the first layer material,
- the first polypropylene is present in the first layer material in a first polypropylene amount in the range of from about 1 wt. % to about 50 wt. % based on the weight of the first layer material,
- the second polyethylene is present in the second layer material in a second polyethylene amount in the range of from about 5 wt. % to about 95 wt. % based on the weight of the second layer material, and
- the second polypropylene is present in the second layer material in a second polypropylene amount in the range of from about 5 wt. % to about 95 wt. % based on the weight of the second layer material.
Dependencies are inferred from the claim text.