Polymer containing sulfo group and organic electroluminescent element containing the polymer
AssigneeYamamoto Chemcials, Inc.
InventorsKazuhiko Togashi, Junko Naruse, Naruyoshi Mita
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Abstract
A polymer compound suitable for use in organic electroluminescent elements; a process for producing the compound; and an organic electroluminescent element employing the compound. The polymer is a sulfo-containing polymer characterized by having a structure formed by introducing sulfo groups into a polymer comprising repeating units represented by the general formula (1): wherein, in the formula, Ar1 and Ar2 each represents a monovalent aromatic group; Y represents a divalent group comprising an aromatic group; and W represents a divalent aromatic group having 4 to 30 carbon atoms.
Claims28
A sulfo group-containing polymer compound having a structure formed by introducing sulfo groups into a polymer compound comprising repeating units represented by the general formula (1),
- wherein, in the formula, Ar1 and Ar2 each represents a monovalent aromatic group;
- Y represents a divalent group comprising an aromatic group;
- W represents a divalent aromatic group having 4 to 30 carbon atoms;
- a group represented by Y is a group represented by the general formula (a), and a group represented by W is a group represented by general formula (b-8),
- Y:
- wherein, in the formula, -Q- is a group selected from the group consisting of a single bond, —O—, —S—, —CH2—, —CMe2-, —CO—, —SO—, —SO2—, —SiH2— and —SiMe2-;
- and m represents an integer of 0 to 2,
- wherein, in the formula (b-8), Z1 to Z4 each represents a substituent;
- p1 and p2 each represents an integer of 0 to 5;
- p3 and p4 each represents an integer of 0 to 4, and wherein at least one of repeating units in which Ar1, Ar2, Y and at least one of four benzene rings bonded to a thiophene ring are substituted with a sulfo group in a polymer chain, in the repeating unit represented by the general formula (2),
- wherein, in the formula, Ar1, Ar2 and Y are the same as the general formula (1);
- Z1 to Z4 each represents a substituent;
- p1 and p2 each represents an integer of 0 to 5;
- p3 and h4 each represents an integer of 0 to 4.
A process for producing a sulfo group-containing polymer compound comprising sulfonating a polymer compound composed of repeating units represented by the general formula (2),
- wherein, in the formula, Ar1 and Ar2 each represents a monovalent aromatic group;
- Y represents a divalent group comprising an aromatic group;
- Z1 to Z4 each represents a substituent;
- p1 and p2 each represents an integer of 0 to 5;
- p3 and p4 each represents an integer of 0 to 4.
Dependencies are inferred from the claim text.