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US 8,012,591 B2Granted
Hydrophilic composition and hydrophilic member
AssigneeFUJIFILM Corporation
InventorsSatoshi Tanaka, Makoto Fukuda, Satoshi Hoshi
Life of this patent
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Abstract
A hydrophilic composition contains (A) a hydrophilic polymer represented by the following general formula (I); and (B) an alkoxide compound of an element selected from Si, Ti, Zr and Al: wherein the symbols in the formula are defined in the specification.
Claims6
A hydrophilic member comprising:
- a substrate;
- a hydrophilic film formed by heating and drying a hydrophilic composition;
- and
- an undercoat layer comprising a nonvolatile catalyst between the substrate and the hydrophilic film,
- wherein the hydrophilic composition comprises:
- (A) a hydrophilic polymer represented by the following general formula (I);
- (B) an alkoxide compound of an element selected from Si, Ti, Zr and Al;
- and
- (C) a catalyst that promotes the reaction of (A) the hydrophilic polymer and (B) the alkoxide compound:
- wherein R1 to R8 each independently represents a hydrogen atom or a hydrocarbon group having 8 or less carbon atoms,
- L2 represents a single bond, or a polyvalent organic linking group having at least one structure selected from the group consisting of —CONH—, —NHCONH—, —OCONH—, —SO,NH— and —SO3—,
- m represents an integer of from 1 to 3,
- x and y represent a polymerization ratio by mol of the repeating units of the formula (I) and the polymerization molar ratio x/y is within a range of from 99/1 to 10/90, and
- wherein
- (a) L1 represents a polyvalent organic linking group comprising from 1 to 200 carbon atoms, provided that at least one —CH2— group is present, and X represents —OH, or
- (b) L1 represents a single bond or a polyvalent organic linking group, and X represents —CON(Rs)(Rb), —NHCORd, —NHCO2Ra, —OCON(Ra)(Rb), —NHCON(Ra)(Rb), —SO3Re, —OSO3Re, —SO2Rd, —NHSO2Rd, —SO2N(Ra)(Rb), —PO3H2, —OPO3H2 or —PO3(Rd)(Re),
- wherein Ra and Rb each independently represents a hydrogen atom or a linear, branched or cyclic alkyl group having from 1 to 8 carbon atoms,
- Rd represents a linear, branched or cyclic alkyl group having from 1 to 8 carbon atoms, and
- Re represents a hydrogen atom, or a linear, branched or cyclic alkyl group having from 1 to 8 carbon atoms, or an alkali metal, an alkaline earth metal, or an onium,
- wherein said hydrophilic film has a surface free energy of 79-85 mN/m.
17 more elements
A hydrophilic member comprising:
- a substrate;
- a hydrophilic film formed by heating and drying a hydrophilic composition;
- and
- an undercoat layer between the substrate and the hydrophilic film, wherein the undercoat layer comprises a nonvolatile catalyst,
- wherein the hydrophilic composition comprises:
- (A) a hydrophilic polymer represented by the following general formula (I) (C) a catalyst that promotes the reaction of (A) the hydrophilic polymer:
- wherein R1 to R8 each independently represents a hydrogen atom or a hydrocarbon group having 8 or less carbon atoms,
- L2 represents a single bond, or a polyvalent organic linking group having at least one structure selected from the group consisting of —CONH—, —NHCONH—, —OCONH—, —SO2NH— and —SO3—,
- m represents an integer of from 1 to 3,
- x and y represent a polymerization ratio by mol of the repeating units of the formula (I) and the polymerization molar ratio x/y is within a range of from 99/1 to 10/90, and
- wherein
- (a) L1 represents a polyvalent organic linking group comprising from 1 to 200 carbon atoms, provided that at least one —CH2— group is present, and X represents —OH, or
- (b) L1 represents a single bond or a polyvalent organic linking group, and X represents —CON(Ra)(Rb), —NHCORd, —NHCO2Ra, —OCON(Ra)(Rb), —NHCON(Ra)(Rb), —SO3Re, —OSO3Re, —SO2Rd, —NHSO2Rd, —SO2N(Ra)(Rb), —PO3H2, —OPO3H2 or —PO3(Rd)(Re),
- wherein Ra and Rb each independently represents a hydrogen atom or a linear, branched or cyclic alkyl group having from 1 to 8 carbon atoms,
- Rd represents a linear, branched or cyclic alkyl group having from 1 to 8 carbon atoms, and
- Re represents a hydrogen atom, or a linear, branched or cyclic alkyl group having from 1 to 8 carbon atoms, or an alkali metal, an alkaline earth metal, or an onium,
- wherein said hydrophilic film has a surface free energy of 79-85 mN/m.
14 more elements
Dependencies are inferred from the claim text.