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US 8,008,239 B2Granted
Acylalkylisethionate esters and applications in consumer products
AssigneeHuntsman Petrochemical Corporation
InventorsPrakasa R. Anantaneni, John Gray, Marty J. Renner, George A. Smith, David C. Lewis, Donald H. Champion, Christopher J. Whewell
Life of this patent
Estimating the term…
Abstract
The present invention provides acylalkylisethionate esters useful in consumer products. The acylalkylisethionate esters are produced by reacting one or more carboxylic acids with one or more alkyl-substituted hydroxyalkyl sulfonates under esterification reaction conditions. The alkyl-substituted hydroxyalkyl sulfonates used as a raw material in producing the esters are prepared by reacting bisulfite with one or more alkylene oxides.
Claims13
An ester anion mixture having surfactant properties useful in formulating personal care cleansing products comprising:
- a) a first ester anion having the structure:
- and
- b) a different second ester anion having the structure:
- in which R is in each occurrence a hydrocarbon group having between about 4 and about 25 carbon atoms, including straight-chain, branched, saturated and unsaturated hydrocarbon groups;
- wherein R1 is an alkyl group selected from the group consisting of:
- C1 to C6 alkyl, and R2 is hydrogen;
- R4 is an alkyl group selected from the group consisting of:
- C1 to C6 alkyl, R3 is hydrogen.
5 more elements
An ester anion mixture having surfactant properties useful in formulating cleansing products which comprises:
- a) a first ester anion having the structure:
- and
- b) a different second ester anion having the structure:
- in which R is any hydrocarbon group having between about 4 and about 25 carbon atoms, including straight-chain, branched, saturated and unsaturated hydrocarbon groups;
- R1 is independently selected from the group consisting of:
- methyl and ethyl;
- R2 is hydrogen;
- R3 is hydrogen;
- and R4 is independently selected from the group consisting of:
- methyl and ethyl.
7 more elements
A composition of matter useful as a concentrate from which cleansing products may be prepared comprising:
- a) a first ester anion of an alkylisethionic acid according to the formula:
- wherein R is a hydrocarbon group having between about 4 and 25 carbon atoms, including straight-chain, branched, saturated, and unsaturated hydrocarbon groups;
- R1 is an alkyl group selected from the group consisting of:
- C1 to C6 alkyl and R2 is hydrogen;
- and
- b) at least one member selected from the group consisting of:
- water, a surfactant and optional ingredient used in preparing the cleansing product;
- and
- c) a different second ester anion having the structure:
- in which R is in each occurrence a hydrocarbon group having between about 4 and about 25 carbon atoms, including straight-chain, branched, saturated and unsaturated hydrocarbon groups;
- R4 is an alkyl group selected from the group consisting of:
- C1 to C6 alkyl, and R3 is hydrogen.
9 more elements
A composition of matter from which personal care cleansing products may be prepared which comprises:
- a) any amount between 99.50% and 0.25% of a first component which comprises
- a first ester anion of an alkylisethionic acid according to the formula:
- in which R is any hydrocarbon group having between about 4 and about 25 carbon atoms, including straight-chain, branched, saturated, and unsaturated hydrocarbon groups;
- R1 is an alkyl group selected from the group consisting of:
- C1 to C6 alkyl, and R2 is hydrogen;
- and
- b) any amount between 99.75% and 0.50% of a second component comprising one or more members selected from the group consisting of:
- fatty acids, alkyl sulfates, an ethanolamine, an amine oxide, alkali carbonates, water, ethanol, isopropanol, pine oil, sodium chloride, sodium silicate, polymers, alcohol alkoxylates, zeolites, perborate salts, alkali sulfates, enzymes, hydrotropes, dyes, fragrances, preservatives, brighteners, builders, polyacrylates, essential oils, alkali hydroxides, water-soluble branched alkylbenzene sulfonates, ether sulfates, alkylphenol alkoxylates, fatty acid amides, alpha olefin sulfonates, paraffin sulfonates, betaines, chelating agents, tallowamine ethoxylates, polyetheramine ethoxylates, ethylene oxide/propylene oxide block copolymers, alcohol ethylene oxide/propylene oxide low foam surfactants, methyl ester sulfonates, alkyl polysaccharides, N-methyl glucamides, alkylated sulfonated diphenyl oxide, and polyethylene glycol;
- and
- c) a different second ester anion having the structure:
- in which R is in each occurrence a hydrocarbon group having between about 4 and about 25 carbon atoms, including straight-chain, branched, saturated and unsaturated hydrocarbon groups;
- R4 is an alkyl group selected from the group consisting of:
- C1 to C6 alkyl, and R3 is hydrogen.
10 more elements
A personal care cleanser comprising a first acylalkylisethionate ester having the formula
- wherein R is a hydrocarbon group having between 4 and 25 carbon atoms;
- R1 is a branched or straight-chain aliphatic C1 to C6 alkyl group and R2 is hydrogen;
- and X is selected from the group consisting of hydrogen, an alkali metal, an alkaline earth metal, zinc, aluminum, ammonium and ammonium ions substituted with one or more organic groups;
- and
- a different second acylalkylisethionate ester having the formula:
- wherein R is a hydrocarbon group having between 4 and 25 carbon atoms;
- R3 is hydrogen and R4 is a branched or straight-chain aliphatic C1 to C6 alkyl group;
- and X is selected from the group consisting of hydrogen, an alkali metal, an alkaline earth metal, zinc, aluminum, ammonium and ammonium ions substituted with one or more organic groups.
5 more elements
A composition of matter comprising:
- (i) a first acylalkylisethionate ester having the formula:
- wherein R is a hydrocarbon group having between 4 and 25 carbon atoms;
- R1 is a branched or straight-chain aliphatic C1 to C6 alkyl group and R2 is is hydrogen;
- and X is selected from the group consisting of hydrogen, an alkali metal, an alkaline earth metal, zinc, aluminum, ammonium and ammonium ions substituted with one or more organic groups;
- and
- (ii) at least one other member selected from the group consisting of:
- amphoteric surfactant;
- zwitterionic surfactant;
- anionic surfactant;
- nonionic surfactant;
- cationic surfactant;
- water and optional ingredient;
- and
- (iii) a different second acylalkylisethionate ester having the formula:
- wherein R is a hydrocarbon group having between 4 and 25 carbon atoms;
- R3 is hydrogen and R4 is a branched or straight-chain aliphatic C1 to C6 alkyl group;
- and X is selected from the group consisting of hydrogen, an alkali metal, an alkaline earth metal, zinc, aluminum, ammonium and ammonium ions substituted with one or more organic groups.
14 more elements
Dependencies are inferred from the claim text.