Method for producing highly condensed solid-phase polyesters
AssigneeLurgi Zimmer GmbH
InventorsBrigitta Otto, Hans Reitz, Holger Bachmann, Klaus Kirsten
Life of this patent
Estimating the term…
Abstract
The invention relates to a continuous or discontinuous method for the production of highly condensed polyesters in the solid state, comprising a crystallization of a polyester material, wherein the crystallization is carried out in the presence of a gas with a dew point of (less than or equal to) ≦approximately −10° C. The invention also relates to a method for the production of polyester formed bodies using the polyester material obtained for the production of bottles, films and high strength threads.
Claims20
Method of producing polyesters having a desired I.V. value, the method comprising:
- a) crystallizing a polyester material in two stages in the presence of a gas with a dew point of less than or equal to −10° C. in the two stages, the first stage being carried out at a lower temperature than the subsequent stage;
- and
- b) setting the dew point of the gas to a particular value to obtain a desired rise of I.V. value of the polyester of
- (i) about 0 dl/g to about 0.02 dl/g and the dew point of the gas is set to about −10° C. to about −20° C.;
- (ii) about 0.02 dl/g to about 0.04 dl/g and the dew point of the gas is set to about −15° C. to about −25° C.;
- (iii) about 0.04 dl/g to about 0.06 dl/g and the dew point of the gas is set to about −20° C. to about −40° C.;
- (iv) about 0.06 dl/g to about 0.08 dl/g and the dew point of the gas is set to about −30° C. to about −55° C.;
- or
- (v) about 0.08 dl/g to about 0.1 dl/g and the dew point of the gas is set to about −45° C. to about −75° C.
Dependencies are inferred from the claim text.