# US 7,976,608 B2 · Method and apparatus for manufacturing low melting point metal fine particles > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,976,608 B2 - Document ID: US7976608B2 - Status: Granted - Kind: B2 - Application number: 11/885,677 - Filed: 2005-03-09 - Published: 2009-06-18 - Granted: 2011-07-12 - Earliest claimed: 2005-03-09 - Assignees: Senju Metal Industry Co., Ltd.; Miyazaki Prefecture - Inventors: Kiyoshi Torigoe; Masataka Shimizu; Kenji Yamamoto; Mitsuhiro Mizozoe; Hoshiro Takahashi; Tomohide Suzuki; Motohiro Murase - Web page: https://patentgrep.com/patent/US7976608B2 ## CPC - B22F 9/08: by casting, e.g. through sieves or in water, by atomising or spraying (using electric discharge B22F9/14) - B23K 35/0244: {Powders, particles or spheres; Preforms made therefrom} - B23K 35/40: Making wire or rods for soldering or welding - B22F 2009/0808: {Mechanical dispersion of melt, e.g. by sieves} - B22F: WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER (making alloys by powder metallurgy C22C); APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER - B23K: SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM ## Abstract In a solder paste which is a mixture of a flux and low melting point metal particles, low melting point metal fine particles manufactured by a conventional method or apparatus therefor include particles having widely varying particle diameters. Accordingly, the solder paste could not completely fill the minute holes in a mask for application to minute solder portions by printing, or mask removability was poor. According to the present invention, a mixture of a heat resistant continuous phase liquid and coarse metal particles in molten state is passed through a porous membrane to form the coarse low melting point metal particles into fine particles with a predetermined diameter. An apparatus according to the present invention comprise a porous membrane between a heating and dispersing mechanism and a cooling mechanism, and a pressure vessel connected to the heating and dispersing mechanism for applying a high pressure to the heating and dispersing mechanism. ## Claims ### Claim 1 A method of manufacturing low melting point metal fine particles comprising applying a pressure to a mixture of coarse droplets of a low melting point metal in a molten state and a heat resistant continuous phase liquid of a substance different from the low melting point metal at a temperature of at least the melting point of the low melting point metal, the pressure being at least sufficient to force the mixture to pass through a porous membrane having at least two penetrating pores, thereby forming the coarse liquid metal droplets into fine liquid metal droplets, including controlling the speed of passage of the coarse liquid metal droplets through the membrane such that the mean particle diameter of the resulting fine liquid metal droplets is within a ran -e which is of the same order or smaller than the more diameter of the porous membrane, and then cooling the fine liquid metal droplets and the heat resistant continuous phase liquid to a temperature equal to or lower than the melting point of the low melting point metal to obtain solid metal fine particles. ### Claim 2 (depends on 1) A method as claimed in claim 1 including passing the fine liquid metal droplets through a porous membrane to increase the uniformity of the particle diameter of the fine liquid metal droplets. ### Claim 3 (depends on 1) A method as claimed in claim 1 wherein the heat resistant continuous phase liquid is mineral oil, vegetable oil, or a glycol. ### Claim 4 (depends on 1) A method as claimed in claim 1 wherein the heat resistant continuous phase liquid contains a dispersion stabilizer. ### Claim 5 (depends on 1) A method as claimed in claim 1 including introducing the mixture of coarse liquid metal droplets and the heat resistant continuous phase liquid to a first side of the porous membrane outside of the pores and applying the pressure to force the mixture through the porous membrane from the first side to a region on a second side of the porous membrane outside of the pores. ### Claim 6 (depends on 5) A method as claimed in claim 5 including preparing the mixture by mixing the coarse liquid metal droplets and the heat resistant continuous phase liquid in a mixing chamber on the first side of the porous membrane. ### Claim 7 (depends on 5) A method as claimed in claim 5 including passing the continuous phase liquid through the membrane a plurality of times. ### Claim 8 (depends on 5) A method as claimed in claim 5 including passing the continuous phase liquid through a plurality of membranes arranged in series. ### Claim 9 (depends on 1) A method as claimed in claim 1 wherein the coarse liquid metal droplets have a mean particle diameter which is larger than the pore diameter of the porous membrane. ### Claim 10 (depends on 1) A method as claimed in claim 1 wherein the mean particle diameter of the fine liquid metal droplets is smaller than the pore diameter of the porous membrane. ### Claim 11 A method of manufacturing low melting point metal fine particles comprising applying a pressure to a mixture of droplets of a low melting point metal in a molten state and a heat resistant continuous phase liquid of a substance different from the low melting point metal at a temperature of at least the melting point of the low melting point metal on an upstream side of a porous membrane to force the mixture to pass through the porous membrane from the upstream side to a downstream side of the porous membrane to reduce the mean particle diameter of the droplets from a first mean particle diameter on the upstream side of the porous membrane to a second mean particle diameter on the downstream side of the porous membrane, the first mean particle diameter being larger than the pore diameter of the porous membrane, and then cooling the mixture after it passes through the porous membrane to a temperature equal to or lower than the melting point of the low melting point metal to obtain solid metal fine particles. ### Claim 12 (depends on 11) A method as claimed in claim 11 including forcing the mixture to pass through the membrane at a speed such that the second mean particle diameter is of the same order or smaller than the pore diameter of the porous membrane. ### Claim 13 (depends on 12) A method as claimed in claim 12 wherein the second mean particle diameter is smaller than the pore diameter of the porous membrane. ### Claim 14 (depends on 11) A method as claimed in claim 11 wherein the continuous phase liquid comprises oil.