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US 7,973,191 B2Granted
Method for the production of dibenz[c,e] [1,2]-oxaphosphorin derivatives, amino-dibenz[c,e] [1,2]-oxaphosphorin and also use thereof
AssigneeEms-Patent AG
InventorsManfred Döring, Brigitte Lindner, Andreas Kaplan
Life of this patent
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Abstract
The invention relates to general syntheses of (6H)-dibenz[c,e] [1,2]-oxaphosphorins which are substituted with nitrogen compounds on the phosphorus atom and comprising commercially available 6H-dibenz[c,e] [1,2]-oxaphosphorin-6-oxides. These nitrogen-containing (6H)-dibenz[c,e] [1,2]-oxaphosphorins can be used as reactive starting substances for further syntheses or as flameproofing agents or as stabilisers.
Claims16
A method of producing a dibenz[c,e] [1,2]-oxaphosphorin compound of the general formula I
- wherein a 6H-dibenz[c,e] [1,2]-oxaphosphorin-6-oxide of the general formula II
- reacts with a compound of the general formula III
- Z-A Formula III
- to form the compound of formula I, wherein in the general formulae I, II and III respectively, independently of each other,
- x and y are 0, 1, 2, 3 or 4,
- R1 and R2 are the same or different and are selected from the group consisting of hydrogen, linear or branched C1-C22 alkyl, linear or branched C1-C22 O-alkyl or O-aryl, alkylsulphonyl, arylsulphonyl, thioaryl, thioalkyl, linear or branched C3-C22 alkenyl, linear or branched C3-C22 alkynyl, linear or branched C1-C22 hydroxyalkyl, linear or branched C3-C22 alkoxycarbonylalkyl, C3-C12 cycloalkyl, C6-C14 aryl, C7-C22 aralkyl, C7-C22 alkylaryl, an optionally substituted piperidin-4-yl group and halogen atoms,
- A is a primary amine, a secondary amine substituted in a similar or mixed manner, a heterocyclic amine or a hydrazine compound, and
- Z is hydrogen, lithium, sodium or potassium.
5 more elements
Dependencies are inferred from the claim text.