Foamer/sulfur scavenger composition and methods for making and using same
AssigneeClearwater International, LLC
InventorsLarry W. Gatlin, Jack Curr, Kevin Smith, Steve Turk
Life of this patent
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Abstract
A new multi-purpose foaming composition having applications in oil field application, industrial applications, waste management applications, or other applications that can be benefited by a foam, is disclosed, where the composition includes a surfactant, a sulfur scavenger and optionally an additive, where the sulfur scavenger and/or additive improve foam characteristics and/or the foam improves an activity of the sulfur scavenger and/or the additives. Method for using and making the foaming compositions are also disclosed, especially, coiled and capillary coiled tubing downhole applications.
Claims19
A method for supply a foaming composition to a downhole fluid comprising the steps of:
- inserting at least one capillary coiled tubing into a well borehole to a desired depth below a fluid level in the borehole and
- injecting an effective amount of a foaming composition to the fluid to produce a foam,
- where the foaming composition comprises from about 20 wt. % to about 80 wt. % at least one surfactant and from about 80 wt. % to about 20 wt. % at least one sulfur scavenging agent and optionally an additive, where the additive is selected from the group consisting of a carbon dioxide control agent, a corrosion inhibitor, a scale inhibitor, an oxygen control agent, a hydrocarbon dispersing agent and mixtures or combinations thereof,
- where the sulfur scavenging agent or the sulfur scavenging agent and the optional additive concentrate in bubble walls in bubbles in the foam,
- where the sulfur scavenger or the sulfur scavenger and the additive improve foam characteristics including foam stability and foam height, while simultaneously the resulting foam improves the activity of the sulfur scavenger or the activity of the sulfur scavenger and the additive, and where the effective amount is sufficient to decrease a fluid column weight increasing well fluids flow out of the well.
A method comprising the steps of:
- injecting into a downhole fluid an aqueous solution comprising a first effective amount of a foaming composition to produce a foam;
- bringing the foam to a surface of the well;
- adding a defoaming agent to the foam at the surface to break the foam and produce a two phase system;
- separating production or organic fluids from the two phase system;
- and
- adding a supplemental effective amount of the foaming composition to reform a foam,
- where the foaming composition comprises from about 20 wt. % to about 80 wt. % at least one surfactant and from about 20 wt. % to about 80 wt. % at least one sulfur scavenging agent and optionally an additive, where the additive is selected from the group consisting of a carbon dioxide control agent, a corrosion inhibitor, a scale inhibitor, an oxygen control agent, a hydrocarbon dispersing agent and mixtures or combinations thereof,
- where the sulfur scavenging agent or the sulfur scavenging agent and the optional additive concentrate in bubble walls in bubbles in the foam,
- where the sulfur scavenger or the sulfur scavenger and the additive improve foam characteristics including foam stability and foam height, while simultaneously the resulting foam improves the activity of the sulfur scavenger or the activity of the sulfur scavenger and the additive, and where the effective amount is sufficient to decrease a fluid column weight increasing well fluids flow out of the well.
A method comprising the steps of:
- injecting into a downhole fluid via coiled tubing an aqueous solution comprising a first effective amount of a foaming composition below a fluid level to produce a foam downhole;
- lifting the foam to a surface of the well;
- separating the foam into an organic phase and an aqueous phase;
- and
- optionally adding a defoaming agent to the foam to facilitate foam separation into the organic and aqueous phases;
- where the foaming composition comprises from about 20 wt. % to about 80 wt. % at least one surfactant and from about 20 wt. % to about 80 wt. % at least one sulfur scavenging agent and optionally an additive, where the additive is selected from the group consisting of a carbon dioxide control agent, a corrosion inhibitor, a scale inhibitor, an oxygen control agent, a hydrocarbon dispersing agent and mixtures or combinations thereof,
- where the sulfur scavenging agent or the sulfur scavenging agent and the optional additive concentrate in bubble walls in bubbles in the foam,
- where the sulfur scavenger or the sulfur scavenger and the additive improve foam characteristics including foam stability and foam height, while simultaneously the resulting foam improves the activity of the sulfur scavenger or the activity of the sulfur scavenger and the additive, and where the effective amount is sufficient to decrease a fluid column weight increasing well fluids flow out of the well.
Dependencies are inferred from the claim text.