Process for producing a hydrocarbon component
AssigneeNeste Oil Oyj
InventorsJukka Myllyoja, Juha Jakkula, Pekka Aalto, Eija Koivusalmi, Johan-Fredrik Selin, Juha Moilanen
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Abstract
The invention relates to a process for producing a new type of high-quality hydrocarbon base oil of biological origin. The process of the invention comprises ketonisation, hydrodeoxygenation, and isomerization steps. Fatty acids and/or fatty acid esters based on a biological raw material are preferably used as the feedstock.
Claims38
A process for producing base oil, said process comprising the steps wherein a feedstock comprising at least one compound selected from the group consisting of triglycerides, carboxylic acids having a carbon number C1-C38, esters of C1-C38 carboxylic acids with C1-C11 alcohols, C1-C38 alcohols, C1-C38 aldehydes, C1-C38 carboxylic acid anhydrides, and metal salts of C1-C38 carboxylic acids, esters of C1-C38 carboxylic acids with C12-C38 alcohols, natural waxes, dicarboxylic acids and polyols, is subjected to a ketonisation step carried out in the presence of metal oxide catalyst under a pressure from 0 to 10 MPa and at a temperature ranging from 100 to 500° C.,
- the ketonisation product is hydrodeoxygenated in the presence of a hydrodeoxygenation catalyst under a hydrogen pressure ranging from 0.1 to 20 MPa at a temperature ranging from 100 to 500° C., and
- after the hydrodeoxygenation step hydroisomerization is carried out under a hydrogen pressure ranging from 1 to 15 MPa at a temperature ranging from 200 to 400° C. in the presence of a hydroisomerization catalyst,
- to give a base oil product comprising branched hydrocarbons having carbon numbers of at least C18, at least 90% by weight of saturated hydrocarbons, 5-20% by weight of mononaphthenes and wherein fused dinaphthenes and polynaphthenes are in a concentration of no more than 1% by weight, and wherein at least 50% by weight of the saturated hydrocarbons have a width of the carbon number range of no more than 9.
A process for producing branched hydrocarbons, said process comprising the steps wherein a feedstock comprising at least one compound selected from the group consisting of triglycerides, carboxylic acids having a carbon number C1-C38, esters of C1-C38 carboxylic acids with C1-C11 alcohols, C1-C38 alcohols, C1-C38 aldehydes, C1-C38 carboxylic acid anhydrides, and metal salts of C1-C38 carboxylic acids, esters of C1-C38 carboxylic acids with C12-C38 alcohols, natural waxes, dicarboxylic acids and polyols, is subjected to a ketonisation step carried out in the presence of metal oxide catalyst under a pressure from 0 to 10 MPa and at a temperature ranging from 100 to 500° C.,
- the ketonisation product is hydrodeoxygenated in the presence of a hydrodeoxygenation catalyst under a hydrogen pressure ranging from 0.1 to 20 MPa at a temperature ranging from 100 to 500° C.,
- and after the hydrodeoxygenation step hydroisomerization is carried out under a hydrogen pressure ranging from 1 to 15 MPa at a temperature ranging from 200 to 400° C. in the presence of a hydroisomerization catalyst.
Dependencies are inferred from the claim text.