High density storage of ammonia
AssigneeAmminex A/S
InventorsTue Johannessen, Christensen Claus Hviid, Norskov Jens Kehlet, Sorensen Rasmus Zink, Quaade Ulrich
Life of this patent
Estimating the term…
Abstract
A solid ammonia storage and delivery material comprising an ammonia absorbing/desorbing solid material, said storage and delivery material having been compacted to a density above 50% of the theoretic skeleton density provides a solid ammonia storage material which is easy to produce and handle and has a very high density of stored ammonia which is readily released under controlled conditions even though the porosity of the material is very low, and which storage material is safe for storage and transport of ammonia without special safety measures.
Claims14
A system for delivery of ammonia to an ammonia consuming unit wherein the system comprises a discharge chamber having a single opening, said opening being used for delivery of ammonia, said chamber comprising a compacted ammonia absorbing/desorbing solid material in the form of one or more compacted units, means for heating said chamber wherein ammonia is released by thermal desorption, and means for conveying the desorbed ammonia from said discharge chamber to one or more ammonia consuming units, wherein said compacted ammonia absorbing/desorbing solid material is selected from an ionic salt of the general formula Ma(NH3)nXz wherein M is one or more cations selected from alkali metals, alkaline earth metals, aluminum, transition metals and combinations thereof, X is one or more anions selected from fluoride, chloride, bromide, iodide, nitrate, thiocyanate, sulphate, molybdate and phosphate ions, a is the number of cations per salt molecule, z is the number of anions per salt molecule, and n is the coordination number of 2 to 12, said ionic salt being compacted to a density above 50% of the theoretical skeleton density, and wherein the volume of a compacted unit of said compacted ammonia absorbing/desorbing solid material ranges from about 1 cm3 to about 1000 liters.
Dependencies are inferred from the claim text.