Catalytic partial oxidation reforming for syngas processing and products made therefrom

A process for producing syngas and one or more hydrocarbon products therefrom, comprising:

• partially oxidizing a first hydrocarbon in the presence of an oxidant and one or more first catalysts at conditions sufficient to partially combust a portion of the first hydrocarbon to provide carbon dioxide, non-combusted first hydrocarbon, and heat;
• reforming at least a portion of the non-combusted first hydrocarbon in the presence of at least a portion of the heat generated in the partial oxidation step and the one or more first catalysts in a catalytic partial oxidation (CPOX) reactor to provide a first syngas comprising hydrogen, carbon monoxide, and carbon dioxide;
• indirectly exchanging heat from the first syngas to a second hydrocarbon to reform at least a portion of the second hydrocarbon in the presence of steam and one or more second catalysts to provide a second syngas comprising hydrogen, carbon monoxide, carbon dioxide, and water;
• and
• reacting the first syngas, the second syngas, or a mixture thereof to provide a tail gas and one or more Fischer-Tropsch products, derivatives thereof, or combinations thereof,
• wherein the composition of the first syngas upon exiting the CPOX reactor comprises from about 30% mol dry basis to about 70% mol dry basis hydrogen, from about 5% mol dry basis to about 35% mol dry basis carbon monoxide, and from about 5% mol dry basis to about 25% mol dry basis carbon dioxide.