Use of metal complex compounds as oxidation catalysts

A detergent, cleaning, disinfecting or bleaching composition comprising

• I) from 1 to 50 wt-%, based on the total weight of the composition, A) of at least one anionic surfactant and/or B) of a non-ionic surfactant,
• II) from 0 to 70 wt-%, based on the total weight of the composition, C) of at least one builder substance,
• III) 1-99 wt-%, based on the total weight of the composition, D) of at least one peroxide and/or one peroxide-forming substance, O2 and/or air,
• IV) E) 0.005 to 2 wt-% of at least one metal complex compound of formula (1),
• V) 0-20 wt-%, based on the total weight of the composition, of at least one further additive, and
• VI) water ad 100 wt-%, based on the total weight of the composition,
• [LnMemXp]zYq (1)
• wherein
• Me is manganese, titanium, iron, cobalt, nickel or copper,
• X is a coordinating or bridging radical,
• n and m are each independently of the other an integer having a value of from 1 to 8,
• p is an integer having a value of from 0 to 32,
• z is the charge of the metal complex,
• Y is a counter-ion,
• q=z/(charge of Y), and
• L is a ligand of formula (2)
• wherein
• s=0 or 1;
• A denotes
• or
• or
• or
• R6 denotes A or hydrogen, C1-C28 alkyl, C2-C28 alkenyl, C2-C22 alkinyl, C3-C12 cycloalkyl, C3-C12 cycloalkenyl, C7-C28 aralkyl, C1-C20 heteroalkyl, C3-C12 cycloheteroalkyl, C5-C16 heteroaralkyl, unsubstituted or substituted aryl or heteroaryl, or OH;
• R′6 denotes hydrogen, C1-C28 alkyl, C2-C28 alkenyl, C2-C22 alkinyl, C3-C12 cycloalkyl, C3-C12 cycloalkenyl, C7-C28 aralkyl, C1-C20 heteroalkyl, C3-C12 cycloheteroalkyl, C5-C16 heteroaralkyl, unsubstituted or substituted aryl or heteroaryl, or OH;
• * signifies the bond/linkage to the structure of formula (2);
• R1 denotes
• or hydrogen, C1-C28 alkyl, C2-C28 alkenyl, C2-C22 alkinyl, C3-C12 cycloalkyl, C3-C12 cycloalkenyl, C7-C28 aralkyl, C1-C20 heteroalkyl, C3-C12 cycloheteroalkyl, C5-C16 heteroaralkyl, cyano, halogen, nitro, or unsubstituted or substituted aryl, or unsubstituted or substituted heteroaryl, —COOR13 or —SO3R13 wherein
• R13 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl;
• or R1 is —SR14, —SO2R14 or —OR14 wherein
• R14 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl;
• or R1 is —NR15R16, —(C1-C6alkylene)-NR15R16, —N⊕R15R16R17, —(C1-C6alkylene)-N⊕R15R16R17, —N(R14)—(C1-C6alkylene)-NR15R16, —N[(C1-C6alkylene)-NR15R16]2, —N(R14)—(C1-C6alkylene)-N⊕R15R16R17, —N[(C1-C6alkylene)-N⊕(R15R16R17]2, —N(R14)—N—R15R16 or ⊕—N(R14)—N⊕R15R16R17, wherein
• R14 is as defined above and
• R15, R16 and R17 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl, or
• R15 and R16, together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms,
• R7 denotes
• or hydrogen;
• C1-C28 alkyl;
• C2-C28 alkenyl, C2-C22 alkinyl, C3-C12 cycloalkyl, C3-C12 cycloalkenyl, C7-C28 aralkyl, C1-C20 heteroalkyl, C3-C12 cycloheteroalkyl, C5-C16 heteroaralkyl, cyano, halogen, nitro, —COOR13 or —SO3R13 wherein
• R13 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl;
• or R7 is —SR14, —SO2R14 or —OR14 wherein
• R14 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl;
• or R7 is —NR15R16, —(C1-C6alkylene)-NR15R16, —N⊕R15R16R17, —(C1-C6alkylene)-N⊕R15R16R17, —N(R14)—(C1-C6alkylene)-NR15R16, —N[(C1-C6alkylene)-NR15R16]2, —N(R14)—(C1-C6alkylene)-N⊕R15R16R17, —N[(C1-C6alkylene)-N⊕R15R16R17]2, —N(R14)—N—R15R16 or —N(R14)—N⊕R15R16R17, wherein
• R14 is as defined above and
• R15, R16 and R17 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl, or
• R15 and R16, together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms;
• * signifies the bond/linkage to A;
• R2, R3, R4, R8, R9, R10, R18, R19, R20, R21, R22, R23, R24, R25, R26, and R27 are each independently of the others hydrogen, unsubstituted or substituted C1-C18alkyl, C2-C28alkenyl, C3-C12cycloalkyl, C3-C12cycloalkenyl or unsubstituted or substituted aryl or unsubstituted or substituted heteroaryl, cyano, halogen, nitro, —OH, —COOR13 or —SO3R13 wherein
• R13 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl;
• or are —SR14, —SO2R14 or —OR14 wherein
• R14 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl;
• or are —NR15R16, —(C1-C6alkylene)-NR15R16, —N⊕R15R16R17, —(C1-C6alkylene)-N⊕R15R16R17, —N(R14)—(C1-C6alkylene)-NR15R16, —N[(C1-C6alkylene)-NR15R16]2, —N(R14)—(C1-C6alkylene)-N⊕R15R16R17, —N[(C1-C6alkylene)-N⊕R15R16R17]2, —N(R14)—N—R15R16 or —N(R14)—N⊕R15R16R17, wherein
• R14 is as defined above and
• R15, R16 and R17 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or unsubstituted or substituted aryl, or
• R15 and R16, together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms and
• R5, R11 and R12 denote independently of each other hydrogen, C1-C28 alkyl, C2-C28 alkenyl, C2-C22 alkinyl, C3-C12 cycloalkyl, C3-C12 cycloalkenyl, C7-C28 aralkyl, C1-C20 heteroalkyl, C3-C12 cycloheteroalkyl, C5-C16 heteroaralkyl, unsubstituted or substituted aryl, or unsubstituted or substituted heteroaryl;
• or
• R1 and R2, and/or R7 and R8 are a group
• or