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US 7,927,671 B2Granted
Trifunctional compound, composition and polymer thereof
AssigneesChisso Corporation, Chisso Petrochemical Corporation
InventorTakashi Kato
Life of this patent
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Abstract
The invention includes compounds represented by Formula (1): wherein Ra is a polymerizable group such as (meth)acryloyloxy, an oxirane ring, an oxetane ring or the like; A is 1,4-cyclohexylene, 1,4-phenylene or the like; Z is a single bond, alkylene having 1 to 20 carbon atoms or the like; Y is a single bond, alkylene having 1 to 20 carbon atoms or the like; and m and n are an integer of 0 to 5.
Claims44
A compound represented by Formula (1):
- wherein in Formula (1), Ra is independently any of the groups represented by Formulas (2-1) to (2-6);
- A is independently 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene, naphthalene-2,6-diyl, tetrahydronaphthalene-2,6-diyl, fluorene-2,7-diyl or bicyclo[2.2.2]octane-1,4-diyl;
- in these rings, optional —CH2— may be replaced by —O—, optional —CH═ may be replaced by —N═ and optional hydrogens may be replaced by halogen, alkyl having 1 to 5 carbon atoms or halogenated alkyl having 1 to 5 carbon atoms;
- Z is independently a single bond or alkylene having 1 to 20 carbon atoms;
- in the alkylene, optional —CH2— may be replaced by —O—, —CO—, —COO—, —OCO—, —CH═H—, —CF═CF— or —C≡C— and optional hydrogen may be replaced by halogen;
- Y is independently a single bond or alkylene having 1 to 20 carbon atoms;
- in the alkylene, optional —CH2— may be replaced by —O—, —CO—, —COO—, —OCO—, —OCOO— or —CH═CH— and optional hydrogen may be replaced by halogen;
- m and n are independently an integer of 0 to 5;
- when all Ra are methacryloyloxy groups, excluded is a case in which m=n=1, two A are 1,4-phenylene, two Z are single bonds, two Y adjacent to A are —(OCH2)4— or —(OCH2CH2)1-10— and remaining Y is —CH2CH2—;
- and wherein in Formulas (2-1) to (2-6), Rb is independently hydrogen, halogen or alkyl having 1 to 5 carbon atoms, and optional hydrogen in the alkyl may be replaced by halogen.
7 more elements
A compound represented by Formula (I) or (II):
- wherein in Formulas (I) and (II),
- Ra, Ra1 and Ra2 are independently any of the groups represented by Formulas (2-1) to (2-6), and Ra1 is not the same as Ra2;
- A is independently 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene, naphthalene-2,6-diyl, tetrahydronaphthalene-2,6-diyl, fluorene-2,7-diyl or bicyclo[2.2.2]octane-1,4-diyl;
- in these rings, optional —CH2— may be replaced by —O—, optional —CH═ may be replaced by —N═ and optional hydrogens may be replaced by halogen, alkyl having 1 to 5 carbon atoms or halogenated alkyl having 1 to 5 carbon atoms;
- Z is independently a single bond or alkylene having 1 to 20 carbon atoms;
- in the alkylene, optional —CH2— may be replaced by —O—, —CO—, —COO—, —OCO—, —CH═CH—, —CF═CF— or —C≡C— and optional hydrogen may be replaced by halogen;
- Y is independently a single bond or alkylene having 1 to 20 carbon atoms;
- in the alkylene, optional —CH2— may be replaced by —O—, —CO—, —COO—, —OCO— or —CH═CH—;
- and optional hydrogen may be replaced by halogen;
- provided that when all Ra in Formula (I) are methacryloyloxy groups, excluded is the case in which two A are 1,4-phenylene, two Z are single bonds, two Y adjacent to A are —(OCH2)4— or —(OCH2CH2)1-10— and remaining Y is —CH2CH2—;
- and wherein in Formulas (2-1) to (2-6), Rb is independently hydrogen, halogen or alkyl having 1 to 5 carbon atoms, and optional hydrogen in the alkyl may be replaced by halogen.
8 more elements
Dependencies are inferred from the claim text.