Ultraviolet-curable resin composition, ultraviolet-curable coating and coated article
AssigneeDIC Corporation
InventorsHiroshi Matsuzawa, Shinichi Kudo
Life of this patent
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Abstract
The present invention is to provides an ultraviolet-curable resin composition which contains a composite resin (A) having a polysiloxane segment (a1) having a silanol group and/or a hydrolytic silyl group as well as a polymerizable double bond and a polymer segment (a2) other than the polysiloxane segment (a1), and a photo initiator (B). The ultraviolet-curable resin composition is able to form a cured coating film excellent in weatherability such as scratch resistance, acid resistance, alkali resistance and solvent resistance, without heating.
Claims13
An ultraviolet-curable resin composition which comprises
- a composite resin (A) which has a polysiloxane segment (a1) having a silanol group and/or a hydrolytic silyl group, as well as a polymerizable double bond and a polymer segment (a2) other than the polysiloxane segment (a1);
- a photo initiator (B);
- and
- a polyfunctional (meta) acrylate,
- wherein the polysiloxane segment (a1) is a polysiloxane segment having a structural unit expressed by the following general formula (S-2) and (S-3),
- (in the general formulae (S-2) and (S-3), R3, R4 and R5 each independently denotes an alkyl group of 1 to 6 carbon atoms, a cycloalkyl group or an aryl group of 3 to 8 carbon atoms and an aralkyl group of 7 to 12 of carbon atoms), and
- wherein the composite resin (A) is a composite resin in which the polysiloxane segment (a1) is bonded to the polymer segment (a2) in a structure expressed by the formula (S-5)
- (in the formula, the carbon atom is a carbon atom constituting the polymer segment (a2), and two silicon atoms are silicon atoms constituting the polysiloxane segment (a1)).
Dependencies are inferred from the claim text.