Electrophotographic photosensitive body
AssigneeHodogaya Chemical Co., Ltd.
InventorsKatsumi Abe, Atsushi Takesue, Takehiro Nakajima, Makoto Koike, Shinya Nagai
Life of this patent
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Abstract
An object of the present invention is to provide an electrophotographic photosensitive body which is not impaired in electrophotographic characteristics such as charged potential and residual potential, and which is also excellent in repeating stability. The present invention provides an electrophotographic photosensitive body including a conductive support having thereon a layer containing a specific p-terphenyl compound and at least one additive.
Claims19
An electrophotographic photosensitive body comprising a conductive support having thereon a layer comprising at least one p-terphenyl compound selected from the following compounds (1) to (5)
- and an additive,
- wherein the additive comprises at least one selected from the group consisting of:
- an organic phosphite compound represented by general formula (A1)
- wherein R1, R2 and R3 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group, with the proviso that the case where R1, R2 and R3 are all hydrogen atoms simultaneously is excluded;
- a triphenylated phosphorus compound represented by general formula (A2)
- wherein R4, R5, R6, R7, R8 and R9 which may be the same or different represent a hydrogen atom, a halogen atom, a hydroxyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group or a substituted or unsubstituted alkyl group;
- a thioether compound represented by general formula (A3)
- R10—S—R11 (A3)
- wherein R10 and R11 which may be the same or different represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group;
- a hydroquinone compound represented by general formula (A4)
- wherein R12, R13, R14 and R15 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted amino group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acyl group, a substituted or unsubstituted silyl group, a substituted or unsubstituted aryloxy group or a substituted or unsubstituted phosphino group;
- a benzotriazole compound represented by general formula (A5)
- wherein R16, R17 and R18 which may be the same or different represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group;
- a benzotriazole-alkylene bisphenol compound represented by general formula (A6)
- wherein R19 represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted aryl group, R20 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted aralkyl group, R21 represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, and R22 and R23 which may be the same or different represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted alkyl aryl group;
- a hydroxybenzophenone compound represented by general formula (A7)
- wherein R24 represents a hydrogen atom or a hydroxyl group, R25 and R26 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group, and R27 represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group;
- a hindered phenol compound represented by general formula (A8)
- wherein R27 represents a substituted or unsubstituted alkyl group, and R28, R29, R30 and R31 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted alkoxy group,
- or general formula (A9)
- wherein R32 represents a substituted or unsubstituted alkyl group, R33, R34 and R35 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted alkoxy group, q is an integer of 2, 3 or 4, and E represents an oxygen atom, a sulfur atom or an aliphatic divalent group when q is 2, represents an aliphatic trivalent group or an aromatic trivalent group when q is 3, and represents an aliphatic tetravalent group when q is 4;
- a hindered amine compound represented by general formula (A10)
- wherein R36, R37, R38 and R39 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, Z represents an atomic group necessary to form a nitrogen-containing heterocycle, wherein in the pair of R36 and R37 and the pair of R38 and R39, one of them may be incorporated into Z to form a double bond, u represents a hydrogen atom, an oxygen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted acyl group, and j represents a hydroxyl group, a substituted or unsubstituted acyloxy group, a substituted or unsubstituted benzoyl group or other organic residues;
- and
- a salicylate compound represented by general formula (A11)
- wherein R40 and R41 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group;
- and
- wherein the layer contains the additive in an amount of from 0.05 to 30 mass % based on the p-terphenyl compound.
An electrophotographic photosensitive body, comprising:
- a conductive support and a layer comprising at least one p-terphenyl compound selected from the group consisting of:
- wherein the layer is present on the conductive support;
- and at least one additive selected from the group consisting of:
- an organic phosphite compound represented by general formula (A1)
- wherein R1, R2 and R3 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group, with the proviso that the case where R1, R2 and R3 are all hydrogen atoms simultaneously is excluded;
- a triphenylated phosphorus compound represented by general formula (A2)
- wherein R4, R5, R6, R7, R8 and R9 which may be the same or different represent a hydrogen atom, a halogen atom, a hydroxyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group or a substituted or unsubstituted alkyl group;
- a thioether compound represented by general formula (A3)
- R10—S—R11 (A3)
- wherein R10 and R11 which may be the same or different represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group;
- a hydroquinone compound represented by general formula (A4)
- wherein R12, R13, R14 and R15 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted amino group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acyl group, a substituted or unsubstituted silyl group, a substituted or unsubstituted aryloxy group or a substituted or unsubstituted phosphino group;
- a benzotriazole compound represented by general formula (A5)
- wherein R16, R17 and R18 which may be the same or different represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group;
- a benzotriazole-alkylene bisphenol compound represented by general formula (A6)
- wherein R19 represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted aryl group, R20 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted aralkyl group, R21 represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, and R22 and R23 which may be the same or different represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted alkyl aryl group;
- a hydroxybenzophenone compound represented by general formula (A7)
- wherein R24 represents a hydrogen atom or a hydroxyl group, R25 and R26 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group, and R27 represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group;
- a hindered phenol compound represented by general formula (A8)
- wherein R27 represents a substituted or unsubstituted alkyl group, and R28, R29, R30 and R31 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted alkoxy group,
- or general formula (A9)
- wherein R32 represents a substituted or unsubstituted alkyl group, R33, R34 and R35 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted alkoxy group, q is an integer of 2, 3 or 4, and E represents an oxygen atom, a sulfur atom or an aliphatic divalent group when q is 2, represents an aliphatic trivalent group or an aromatic trivalent group when q is 3, and represents an aliphatic tetravalent group when q is 4;
- a hindered amine compound represented by general formula (A10)
- wherein R36, R37, R38 and R39 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, Z represents an atomic group necessary to form a nitrogen-containing heterocycle, wherein in the pair of R36 and R37 and the pair of R38 and R39, one of them may be incorporated into Z to form a double bond, u represents a hydrogen atom, an oxygen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted acyl group, and j represents a hydroxyl group, a substituted or unsubstituted acyloxy group, a substituted or unsubstituted benzoyl group or other organic residues;
- and
- a salicylate compound represented by general formula (A11)
- wherein R40 and R41 which may be the same or different represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group;
- and
- wherein the layer contains the additive in an amount of from 0.05 to 30 mass % based on the p-terphenyl compound.
Dependencies are inferred from the claim text.