Method and apparatus for preparing and supplying catalyst slurry to a polymerization reactor
AssigneeTotal Petrochemicals Research Feluy
InventorLouis Fouarge
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Abstract
The present invention relates to an apparatus for preparing and supplying catalyst to an ethylene slurry loop polymerisation reactor and to an apparatus for controlling the injection of catalyst slurry in a polymerization reactor wherein polyethylene is prepared. The present invention a Iso relates to a method for optimising catalyst supply to a polymerisation reactor. The diluted catalyst is transferred to the reactor (1) using a membrane pump (5) controllable in function of the concentration of a reactant in said reactor (1).
Claims22
A system for supplying a polymerization catalyst to a polymerization reactor comprising:
- a) a storage vessel adapted to contain a concentrated catalyst slurry of solid catalyst particles in a diluent liquid;
- b) a mixing vessel connected to said storage vessel by at least one slurry conduit extending from said storage vessel to said mixing vessel;
- c) a transfer conduit extending from said mixing vessel to provide for the transfer of catalyst slurry from said mixing vessel to said polymerization reactor;
- d) a diluent supply line for supplying a diluent liquid to said concentrated catalyst slurry to provide for a diluted catalyst slurry in said mixing vessel;
- e) a cocatalyst storage vessel adapted to contain a cocatalyst;
- f) a cocatalyst supply line extending from said cocatalyst storage vessel to said transfer conduit to bring said cocatalyst into contact with said diluted catalyst slurry;
- g) an enlarged contact vessel interfaced in said transfer conduit between the connection of said cocatalyst supply line to said transfer conduit and said polymerization reactor.
A system for supplying a polymerization catalyst to a polymerization reactor comprising:
- a) at least two storage vessels adapted to contain a concentrated catalyst slurry;
- each of said storage vessels having an inlet line adapted to receive a concentrated slurry of catalyst particles;
- b) slurry conduits extending from each of said storage vessels to a mixing vessel and provided with metering valves to control the flow rate of catalyst slurry to said mixing vessel;
- c) a transfer conduit extending from said mixing vessel to said polymerization reactor;
- d) a diluent line connected to said transfer conduit for supplying diluent to said transfer conduit;
- and
- e) a dump vessel adapted to receive catalyst waste and an input line to said dump vessel extending from at least one of said mixing vessel and said slurry transfer conduits.
A method for supplying a catalyst to an ethylene loop polymerization reactor comprising:
- a) providing a concentrated slurry of olefin polymerization catalyst particles in a storage vessel;
- b) supplying said concentrated catalyst slurry from said storage vessel through a slurry conduit to a mixing vessel;
- c) adding a diluent liquid to said concentrated catalyst slurry in order to provide a diluted catalyst slurry in said mixing vessel;
- d) withdrawing said diluted catalyst slurry from said mixing vessel and supplying said diluted catalyst slurry through a transfer conduit to a slurry loop polymerization reactor in which ethylene is polymerized;
- e) mixing a cocatalyst with said diluted catalyst slurry prior to supplying said diluted catalyst slurry to said slurry loop polymerization reactor;
- and
- f) subsequent to the mixing of said cocatalyst with said diluted catalyst slurry passing said diluted catalyst slurry containing said cocatalyst through a section of said transfer conduit to provide for an increased contact time of said cocatalyst with said dilute catalyst slurry prior to the introduction of said catalyst slurry into said polymerization reactor.
Dependencies are inferred from the claim text.