Process for production of substituted cyclopentanone
AssigneeAsahi Kasei Chemicals Corporation
InventorsKatsuya Shimizu, Fumio Matsushita
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Abstract
A substituted cyclopentanone represented by the following formula (2): (wherein R3 and R4 represent a substituent having 1 to 8 carbon atoms, may be the same as R1 and R2, respectively, and may be the same as each other) can be produced by hydrogenating the double bond in a compound represented by the following formula (1): (wherein R1 and R2 represent a substituent having 1 to 8 carbon atoms) in the presence of a transition metal catalyst by using a carboxylic acid or a specific concentration of a carboxylic acid ester as a solvent. This process can produce a substituted cyclopentanone which is useful as a jasmine fragrance, an intermediate thereof or the like, in a simple and inexpensive manner at a high cis-isomer ratio.
Claims6
A process for producing a substituted cyclopentanone represented by the formula (2):
- (wherein R1 and R2 represent a substituent having 1 to 8 carbon atoms and may be the same as each other) characterized by hydrogenating the double bond in the five-membered ring of a compound represented by the formula (1):
- in the presence of a transition metal catalyst by using a carboxylic acid as a solvent.
Dependencies are inferred from the claim text.