Polymers and polymer coatings
AssigneeCornell Research Foundation, Inc.
InventorsChristopher K. Ober, Sitaraman Krishnan, Qin Lin
Life of this patent
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Abstract
The invention provides polymers, methods of preparing polymers, and compositions that include polymers, wherein said polymers include a plurality of two-carbon repeating units in a polymer chain, wherein one or more of the two-carbon repeating units of the polymer chain have a substituent that is covalently bonded to a semifluorinated alkyl ethoxy moiety, and the semifluorinated alkyl ethoxy moiety is attached to the polymer chain substituent through an ester, amide, ketone, carbamate, amine, or other suitable linking group. The polymers can be used to provide antifouling coatings.
Claims15
A polymer comprising a plurality of two-carbon repeating units in a polymer chain, wherein one or more of the two-carbon repeating units of the polymer chain have a substituent that is covalently bonded to a moiety of formula Z:
- wherein
- q is independently 1 to about 25;
- r is independently 0 to about 18;
- and
- the moiety of formula Z is attached to the polymer chain substituent through an ester, amide, ketone, carbamate, or amine.
A polymer comprising formula I:
- wherein m1 is about 5 to about 2000;
- m2 is absent or is independently about 5 to about 2000;
- n1 is about 5 to about 2,000;
- n2 is absent or is independently about 5 to about 2000;
- n3 is absent or is independently about 5 to about 2000;
- the dispersement of each individual n1, n2, and n3 subunit on either side of either z* is random and each individual n1, n2, and n3 subunit occurs interchangeably with any other n1, n2, or n3 subunit within the brackets of formula I;
- each R1 is independently hydrogen or methyl and each R2 is independently hydrogen or methyl provided that at least one of R1 and R2 within each n subunit is hydrogen;
- each R3 is independently H, OH, or halo;
- or
- alkyl wherein alkyl is optionally at least partially fluorinated;
- alkyl-terminated (-ethylene glycol-)n wherein n is about 2 to about 24;
- wherein each alkyl or alkyl-terminated (-ethylene glycol-)n is covalently bonded to the carbon of R3 through an ester, amide, or amino group;
- or
- a moiety of formula Z:
- wherein each X is independently —O—C(═O)—CH2—O—, —NH—C(═O)—CH2—O—, or —NH—, linking the moiety of formula Z to the carbon attached to R3, each q is independently 1 to about 25, and each r is independently 1 to about 18;
- provided that at least one R3 of formula I is a moiety of formula Z;
- each R4 and R5 is independently hydrogen, R3, or absent, provided that when R4 is hydrogen, R5 is R3;
- and when R4 is R3, R5 is hydrogen;
- and
- each individual bond represented by - - - is an optional double bond, provided that when the bond between the carbons of R4 and R5 is present, R4 and R5 are absent.
Dependencies are inferred from the claim text.