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US 7,842,771 B2Granted
Self-adhesive addition-crosslinking silicone compositions
AssigneeWacker Chemie AG
InventorArmin Fehn
Life of this patent
Estimating the term…
Abstract
Self-adhesive addition-crosslinking silicone compositions contain (A) at least one diorganopolysiloxane, (B) at least one SiH-containing crosslinker containing a defined fraction of radicals, with the proviso that the viscosity of the organohydropolysiloxane (B) as determined at 25° C. is 5 mPa·s to 5 Pa·s, (C) at least one organohydrooligosiloxane, and (D) at least one hydrosilylation catalyst.
Claims8
A self-adhesive addition-crosslinking silicone composition comprising
- (A) 100 parts by weight of at least one diorganopolysiloxane of the formula (1)
- R1aR2bSiO(4-a-b)/2 (1)
- in which
- R1 is hydroxyl radical or a monovalent, optionally halogen-substituted C1-20 hydrocarbon radical optionally containing O, N, S or P atoms, and being free from aliphatically unsaturated groups,
- R2 is a monovalent, aliphatically unsaturated, optionally halogen-substituted C2-10 hydrocarbon radical optionally containing O, N, S or P atoms,
- b is from 0.0003 to 2,
- with the provisos that 1.5<(a+b)≦3.0, that per molecule there are on average at least two aliphatically unsaturated radicals R2, and that the viscosity of the diorganopolysiloxanes (A) as determined at 25° C. is 1 mPa·s to 40,000 Pa·s,
- (B) 1-5 parts by weight of at least one organohydropolysiloxane of the formula (2)
- R3cR4dR5eHfSiO(4-c-d-2e-f)/2 (2)
- where
- R3 is a monovalent aliphatically saturated C1-10 hydrocarbon radical,
- R4 (a) is an optionally halogen-substituted monovalent C6-20 hydrocarbon radical which contains at least one aromatic C6 ring, and/or
- (b) is a halogen-substituted, saturated monovalent C2-20 hydrocarbon radical optionally containing O or N atoms,
- R5 is an optionally halogen-substituted C6-24 hydrocarbon radical optionally containing O, N, S or P atoms which is divalent and is Si-bonded at both ends,
- c and f are positive numbers, and
- d and e are zero or a positive number,
- with the provisos that d and e cannot simultaneously be zero, that the viscosity of the organohydropolysiloxane (B) as determined at 25° C. is 5 mPa·s to 5 Pa·s, and the organohydrogensiloxane (B) contains per molecule 5 to 18 SiH groups and less than 12 mol percent phenyl groups,
- (C) 0.1 to 3 parts by weight of at least one organohydrooligosiloxane of the formula (3),
- (R6HSiO)n (3),
- where
- R6 is a monovalent, optionally halogen-substituted C1-10 hydrocarbon radical, and
- n is 4, 5, 6, 7, or 8,
- (D) 1×10−5 to 1×10−2 parts by weight of at least one hydrosilylation catalyst.
20 more elements
Dependencies are inferred from the claim text.