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US 7,834,073 B2Granted
Stable solutions of N-substituted aminopolysiloxanes, their preparation and use
AssigneeEvonik Degussa GmbH
InventorsBurkhard Standke, Peter Jenkner
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Abstract
Stable low chloride solutions of hydrosalts of an organic acid with a N-substituted aminopolysiloxane in the form of a T structural unit contain at least one lower alcohol, and at least one stabilizer. Methods to prepare the stable low-chloride solutions are also provided.
Claims17
A stable solution comprising:
- at least one lower alcohol;
- at least one stabilizer;
- and
- at least one hydrosalt of an organic acid with a N-substituted aminopolysiloxane of formula (I)
- wherein
- each R is independently benzyl or vinylbenzyl,
- each Y is independently alkoxy, hydroxyl or O1/2,
- A is an organic carboxylic acid,
- a is 0, 1 or 2,
- b is 0 or 1,
- c is greater than or equal to 0.125,
- (a+b) is from 0.125 to 3, and
- x is equal to or greater than 2;
- and
- the at least one hydrosalt of an organic acid with a N-substituted aminopolysiloxane of formula (I) comprises a T structural unit of the formula:
- wherein
- R′ is [Ra-NH(2-a)(CH2)2NH(1-b)Rb—(CH2)3-] or is of formula (II), with the proviso that at least one of the R′ groups is of formula (II):
- wherein
- z≧1,
- a is 0, 1 or 2, and
- b is 0 or 1;
- a % by weight of chloride based on the total weight of the solution is less than 1%, and
- the at least one stabilizer is selected from the group consisting of 3,5-di-tert-butylcatechol, 2,5-di-tert-butylhydroquinone, 4-tert-butylpyrocatechol, 2,4-di-tert-butylphenol, hydroquinone monomethyl ether, 2,6-di-tert-butyl-p-cresol and a mixture thereof.
20 more elements
Dependencies are inferred from the claim text.