Water-based inks for ink-jet printing
AssigneeKao Corporation
InventorsYasuhiro Doi, Yasushi Ito
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Abstract
The present invention relates to a water-based ink for ink-jet printing which not only satisfies a high optical density but also exhibits an excellent high lighter-fastness; and a water dispersion used for the water-based ink. There are provided a water dispersion for ink-jet printing containing (A) a pigment and (B) water-insoluble polymer particles produced by polymerizing an ethylenically unsaturated monomer containing 25 to 85% by weight of an aromatic group-containing monomer in the presence of a reactive surfactant; and a water-based ink containing the water dispersion.
Claims16
A water-base ink for ink-jet printing, comprising:
- a water dispersion comprising (A) a pigment and (B) water-insoluble polymer particles produced by polymerizing ethylenically unsaturated monomers containing 30 to 75% by weight of an aromatic group-containing monomer in the presence of a reactive sulfonated surfactant,
- where the (A) pigment is a self-dispersible carbon black,
- the reactive sulfonated surfactant is a sulfosuccinic ester-containing surfactant, and
- the glass transition temperature of the polymer of the (B) water-insoluble polymer particles is −40° C. or higher and 30° C. or lower.
A water-base ink for ink jet printing, comprising:
- a water dispersion comprising (A) a pigment and (B) water-insoluble polymer particles in a weight ratio [the pigment (A)/the water-insoluble polymer particles (B)] of the pigment (A) to the water-insoluble polymer particles (B) is 20/80 to 90/10,
- wherein the water-insoluble polymer particles are produced by polymerizing ethylenically unsaturated monomers containing 30 to 75% by weight of styrene (a) and 10 to 68% by weight of 2-ethylhexyl (meth)acrylate monomer (c), and acrylic acid (e) in the presence of a reactive sulfonated surfactant,
- wherein the weight ratio [(a)/(c)] of the constitutional unit derived from the aromatic group-containing monomer (a) to the constitutional unit derived from the 2-ethylhexyl (meth)acrylate (c) is from 0.4 to 5
- where the (A) pigment is a self-dispersible carbon black,
- the reactive sulfonated surfactant is at least one sulfosuccinic ester-containing surfactant selected from the group consisting of a compound represented by the following formulae (4) and (5):
- wherein M2 is Na, K or NH4;
- and R8 is an alkyl group having 8 to 18 carbon atoms;
- and
- wherein M2 is Na, K or NH4 and R8 is an alkyl group having 8 to 18 carbon atoms;
- wherein the reactive surfactant is present in an amount of from 0.1 to 3 parts by weight in the water-insoluble polymer particles (B), wherein parts by weight is calculated on the total parts of ethylenically unsaturated monomers;
- and
- wherein the glass transition temperature of the polymer of the (B) water-insoluble polymer particles is −40° C. or higher and 30° C. or lower.
Dependencies are inferred from the claim text.