Systems and processes for reducing NOx emissions

A system for reducing NOx emissions, comprising:

• a reformer configured to receive a fuel and produce a hydrogen-enriched stream, wherein the hydrogen-enriched stream comprises carbon monoxide, carbon dioxide, the fuel, and less than or equal to about 10 volume percent hydrogen;
• a separation unit in fluid communication with the reformer, wherein the separation unit is configured to receive the hydrogen-enriched stream to separate the carbon dioxide from the hydrogen-enriched stream and produce a carbon dioxide-rich stream;
• a combustion system in fluid communication with the reformer and the separation unit comprising:
• a combustor comprising a first stage and a second stage configured to receive the hydrogen-enriched stream and the carbon dioxide-rich stream, wherein the hydrogen-enriched stream is combusted in the first stage and the carbon dioxide-rich stream is injected in the second stage where the hydrogen-enriched stream is further combusted, and wherein the combustor produces heat energy and a hot compressed mixed gas stream;
• and
• a gas turbine generator in fluid communication with the combustor, wherein the gas turbine generator is configured to expand the hot compressed mixed gas stream and produce electrical energy and an exhaust stream;
• and
• a recuperator in fluid communication with the combustion system configured to recover the heat energy from the combustor and the exhaust stream, wherein the recovered heat is recycled back to the reformer.

A process for reducing NOx emissions, comprising:

• reforming with a reformer a fuel to produce a hydrogen enriched stream, wherein the hydrogen-enriched stream comprises carbon monoxide, carbon dioxide, the fuel, and less than or equal to about 10 volume percent hydrogen;
• separating the carbon dioxide from the hydrogen-enriched stream with a separation unit to produce a carbon dioxide-rich stream;
• combusting in a first stage of a combustor the hydrogen-enriched stream;
• injecting in a second stage of the combustor the carbon dioxide-rich stream for further combusting of the hydrogen-enriched stream, wherein combusting in the first stage and the second stage produces heat energy and a hot compressed mixed gas stream;
• expanding the hot compressed mixed gas stream to produce electricity and an exhaust stream;
• recovering the heat energy from the combustor and exhaust stream;
• and
• recycling the recovered heat energy to the reformer.

A system for reducing NOx emissions, comprising:

• a reformer configured to receive a fuel and produce a hydrogen-enriched stream, wherein the hydrogen-enriched stream comprises less than or equal to about 10 volume percent hydrogen;
• a combustion system configured to burn the hydrogen-enriched stream and produce electricity and an exhaust stream;
• and
• a recuperator configured to recover heat from the exhaust stream, wherein the recovered heat is recycled back to the reformer;
• and
• a second reformer configured to receive the fuel and produce a carbon dioxide-rich stream, wherein the carbon dioxide-rich stream is burned in the combustion system.