Shape memory main-chain smectic-C elastomers
AssigneeUniversity of Connecticut
InventorsPatrick T. Mather, Ingrid A. Rousseau, Haihu Qin
Life of this patent
Estimating the term…
Abstract
Shape memory main-chain smectic-C elastomers are described, as are methods for their preparation and monomers used in such methods. The elastomers are prepared by hydrosilylation of a reaction mixture including a liquid crystalline diene, a crosslinking agent, and a bis(silyl hydride) compound. The elastomers exhibit shape-memory properties and spontaneously reversible shape changes. They are useful for fabrication of shape memory articles including, for example, implantable medical devices, contact lenses, reversible embossing media, and Fresnel lenses.
Claims8
A composition, comprising:
- a mesogenic diene having the structure
- wherein each occurrence of R2 is tertiary butyl, and wherein each occurrence of r, s, and t is independently 0 or 1 with the proviso that one and only one of r, s, and t is 1;
- and
- wherein each occurrence of m is independently 1 to about 10.
Dependencies are inferred from the claim text.