Wide mesoporous alumina composites having trimodal pore structure
AssigneeUop LLC
InventorVladislav I. Kanazirev
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AssigneeUop LLC
InventorVladislav I. Kanazirev
Estimating the term…
Wide mesoporous alumina composites are produced by an “in situ reaction” route comprising agglomeration of an alumina powder that is capable of rehydration together with a second reactive powder such as carbonate. In one method of production, the powders are fed to a rotating forming device that is continuously sprayed with liquid under conditions to form particulates. The discharging beads are then subjected to curing and thermal activation to produce the final catalyst or adsorbent. The alumina participates in a pore altering process involving the carbonate component upon formation of hydroxycarbonate intermediates such as Dawsonite. Large fraction of the pore volume of the final product consists of wide mesopores in the 15-50 nanometers range. The alumina composites exhibit a characteristic trimodal pore structure that includes also small micro-meso pores and macropores larger than 200 nanometers.
A process for the removal of at least one hydrogen halide from a gaseous or liquid stream comprising hydrocarbons or a product stream of a synthesis gas reaction wherein said process comprises contacting said gaseous or liquid stream with a sorbent material, wherein said sorbent material exhibits a trimodal pore distributions with 40-49% of pores are between 15 and 50 nm and said sorbent material comprises an alumina.
Dependencies are inferred from the claim text.