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US 7,790,057 B2Granted
Electroluminescent polymers and use thereof
AssigneeMerck Patent GmbH
InventorsArne Büsing, Holger Heil, Aurélie Ludemann, Niels Schulte
Life of this patent
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Abstract
The present invention relates to electroluminescent polymers which contain structural units of the formula (1) and to the use thereof. The polymers according to the invention exhibit improved efficiency and a longer lifetime, in particular on use in polymeric organic light-emitting diodes.
Claims19
A polymer containing units of the formula (I)
- in which
- R is on each occurrence, identically or differently, H, a straight-chain alkyl chain having 1 to 40 C atoms, a branched alkyl chain having 3 to 40 C atoms or a cyclic alkyl chain having 3 to 40 C atoms, each of which is optionally substituted by R1 and in which, in addition, one or more non-adjacent C atoms is optionally replaced by ═N—R1, —O—, —S—, —O—CO—O—, —CO—O—, —CR1═CR1— or —C≡C— and in which, in addition, one or more H atoms is optionally replaced by F, Cl, Br, I or CN, or an aromatic ring system having 5 to 40 C atoms or a heteroaromatic ring system having 2 to 40 C atoms, which is optionally substituted by one or more radicals R1;
- the two radicals R here optionally form a further mono- or polycyclic, aromatic or aliphatic ring system with one another;
- R1 is on each occurrence, identically or differently, H, a straight-chain alkyl chain having 1 to 22 C atoms, a branched alkyl chain having 3 to 22 C atoms or a cyclic alkyl chain having 3 to 22 C atoms, in which, in addition, one or more non-adjacent C atoms is optionally replaced by ═N—R2, —O—, —S—, —O—CO—O—, —CO—O—, —CR2═CR2— or —C≡C— and in which, in addition, one or more H atoms is optionally replaced by F, Cl, Br, I or CN, or an aryl, heteroaryl, aryloxy or heteroaryloxy group having 5 to 40 C atoms, which is optionally substituted by one or more non-aromatic radicals R1;
- two or more of the radicals R1 here optionally form a ring system with one another and/or with R;
- or F, Cl, Br, I, CN, N(R2)2, Si(R2)3 or B(R2)2;
- R2 is on each occurrence, identically or differently, H or an aliphatic or aromatic hydrocarbon radical having 1 to 20 C atoms;
- X is on each occurrence, identically or differently, B, C, N, O, P, S, Se, P═O, S═O or SO2;
- n is on each occurrence, identically or differently, 0, 1, 2 or 3;
- m is on each occurrence, identically or differently, 0, 1 or 2;
- and
- the dashed bond denotes the link in the polymer and with the proviso that
- if X is O then there are no Rs present and if X is N or B, then there is only one R present and if X is S or P═O then there can be no Rs present.
10 more elements
Dependencies are inferred from the claim text.